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Anomalously strong ...
Anomalously strong two-electron one-photon X-ray decay transitions in CO caused by avoided crossing
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- Couto, Rafael C. (author)
- KTH,Teoretisk kemi och biologi,Royal Inst Technol, Sch Biotechnol, Theoret Chem & Biol, S-10691 Stockholm, Sweden.;Univ Fed Goias, Inst Quim, Campus Samambaia,CP 131, BR-74001970 Goiania, Go, Brazil.
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- Guarise, Marco (author)
- Lab Nacl Luz Sincrotron, BR-10000 Campinas, Brazil.;Univ Paris 06, Univ Paris 04, Lab Chim Phys Matiere & Rayonnement, UMR7614, F-75005 Paris, France.
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- Nicolaou, Alessandro (author)
- Synchrotron SOLEIL, BP 48, F-91192 Gif Sur Yvette, France.
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- Jaouen, Nicolas (author)
- Synchrotron SOLEIL, BP 48, F-91192 Gif Sur Yvette, France.
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- Chiuzbaian, Gheorghe S. (author)
- Univ Paris 06, Univ Paris 04, Lab Chim Phys Matiere & Rayonnement, UMR7614, F-75005 Paris, France.
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- Luening, Jan (author)
- Univ Paris 06, Univ Paris 04, Lab Chim Phys Matiere & Rayonnement, UMR7614, F-75005 Paris, France.
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- Ekholm, Victor (author)
- Uppsala universitet,Molekyl- och kondenserade materiens fysik
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- Rubensson, Jan-Erik (author)
- Uppsala universitet,Molekyl- och kondenserade materiens fysik
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- Såthe, Conny (author)
- Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory,Lund Univ, MAX Lab 4, Box 118, S-22100 Lund, Sweden.
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- Hennies, Franz (author)
- Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory,Lund Univ, MAX Lab 4, Box 118, S-22100 Lund, Sweden.
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- Kimberg, Victor (author)
- KTH,Teoretisk kemi och biologi,Royal Inst Technol, Sch Biotechnol, Theoret Chem & Biol, S-10691 Stockholm, Sweden.
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- Guimaraes, Freddy F. (author)
- Univ Fed Goias, Inst Quim, Campus Samambaia,CP 131, BR-74001970 Goiania, Go, Brazil.
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- Ågren, Hans (author)
- KTH,Teoretisk kemi och biologi,Royal Inst Technol, Sch Biotechnol, Theoret Chem & Biol, S-10691 Stockholm, Sweden.
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- Gel'mukhanov, Faris (author)
- KTH,Teoretisk kemi och biologi,Royal Inst Technol, Sch Biotechnol, Theoret Chem & Biol, S-10691 Stockholm, Sweden.
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- Journel, Loic (author)
- Univ Paris 06, Univ Paris 04, Lab Chim Phys Matiere & Rayonnement, UMR7614, F-75005 Paris, France.
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- Simon, Marc (author)
- Univ Paris 06, Univ Paris 04, Lab Chim Phys Matiere & Rayonnement, UMR7614, F-75005 Paris, France.
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(creator_code:org_t)
- 2016-02-10
- 2016
- English.
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In: Scientific Reports. - : Nature Publishing Group. - 2045-2322. ; 6
- Related links:
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https://doi.org/10.1...
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http://dx.doi.org/10... (free)
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Abstract
Subject headings
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- The unique opportunity to study and control electron-nuclear quantum dynamics in coupled potentials offered by the resonant inelastic X-ray scattering (RIXS) technique is utilized to unravel an anomalously strong two-electron one-photon transition from core-excited to Rydberg final states in the CO molecule. High-resolution RIXS measurements of CO in the energy region of 12-14 eV are presented and analyzed by means of quantum simulations using the wave packet propagation formalism and ab initio calculations of potential energy curves and transition dipole moments. The very good overall agreement between the experimental results and the theoretical predictions allows an in-depth interpretation of the salient spectral features in terms of Coulomb mixing of "dark" with "bright" final states leading to an effective two-electron one-photon transition. The present work illustrates that the improved spectral resolution of RIXS spectra achievable today may call for more advanced theories than what has been used in the past.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Couto, Rafael C.
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Guarise, Marco
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Nicolaou, Alessa ...
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Jaouen, Nicolas
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Chiuzbaian, Gheo ...
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Luening, Jan
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show more...
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Ekholm, Victor
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Rubensson, Jan-E ...
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Såthe, Conny
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Hennies, Franz
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Kimberg, Victor
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Guimaraes, Fredd ...
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Ågren, Hans
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Gel'mukhanov, Fa ...
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Journel, Loic
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Simon, Marc
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Atom and Molecul ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
- Articles in the publication
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Scientific Repor ...
- By the university
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Royal Institute of Technology
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Lund University
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Uppsala University