Origin of fine structures on the dissociative 1s ->sigma* resonance in X-ray absorption spectra of O-2

• We attempt to explain a puzzling long-tailed peak shape of the X-ray absorption spectrum of the oxygen molecule in the energy region around 539 eV taking into account the Rydberg-valence and vibronic couplings. The long-tailed feature is found to arise from two dissociative sigma* states and the sudden drop in intensity is related to decrease in transition dipole near the crossing point between the repulsive sigma* and weak 3s Rydberg states with the quartet ion cores. This is supported by numerical wave-packet simulations allowing for all interchannel couplings between the Rydberg and valence manifolds with the quartet and doublet ion cores in a diabatic representation of the core-excited states.

Nyckelord

k-edge spectra

raman-scattering

high-resolution

spectroscopy

valence

excitation

dynamics

molecule

o2

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