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Nanoengineered BSCF...
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Darab, MahdiKTH,Funktionella material, FNM
(författare)
Nanoengineered BSCF Cathode Materials for Intermediate-Temperature Solid-Oxide Fuel Cells
- Artikel/kapitelEngelska2009
Förlag, utgivningsår, omfång ...
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The Electrochemical Society,2009
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printrdacarrier
Nummerbeteckningar
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LIBRIS-ID:oai:DiVA.org:kth-18589
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-18589URI
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https://doi.org/10.1149/1.3142430DOI
Kompletterande språkuppgifter
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Språk:engelska
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Sammanfattning på:engelska
Ingår i deldatabas
Klassifikation
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Ämneskategori:ref swepub-contenttype
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Ämneskategori:art swepub-publicationtype
Anmärkningar
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QC 20100525
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A recently reported promising cathode material for solid-oxide fuel cells (SOFCs), namely, BaxSr1-xCoyFe1-yO3-delta (BSCF) is fabricated in nanocrystalline form by a chemical alloying approach. The approach is comprised of solution chemical synthesis of a precursor and its thermochemical processing toward the desired phase. All the constituent elements, Ba, Sr, Co, and Fe, were coprecipitated from an aqueous solution of their salts to produce a precursor with a well-defined composition, fine particle size, high homogeneity, and high reactivity. After calcining and sintering at 1000 degrees C, the individual oxides were alloyed into nanostructured perovskite (with x=0.5 and y=0.2) Ba0.5Sr0.5Co0.2Fe0.8O3 of high purity. Spark plasma sintering was used for compaction to preserve the material's nanostructure, and sintered compacts demonstrated a significant increase in electrical conductivity values at temperatures up to 900 degrees C, compared to the earlier reports. The measured conductivity values are sufficiently high for cathode applications with a maximum of about 63 S cm(-1) at 430 degrees C in air and 25 S cm(-1) at 375 degrees C in N-2, respectively. These values are about twice as high as conventional BSCF mainly due to the reduction in interfacial resistance, implying a high promise for nanoengineered BSCF as cathode material at low or intermediate-temperature SOFCs.
Ämnesord och genrebeteckningar
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alloying
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barium compounds
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calcination
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cobalt compounds
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electrical
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conductivity
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electrochemical electrodes
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nanostructured materials
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nanotechnology
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particle size
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plasma materials processing
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sintering
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solid oxide fuel cells
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strontium compounds
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surface resistance
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thermochemistry
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electrical-properties
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phase-structure
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ba0.5sr0.5co0.8fe0.2o3-delta
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performance
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sofcs
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conductivity
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membranes
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Toprak, Muhammet S.KTH,Funktionella material, FNM(Swepub:kth)u1u3m5a2
(författare)
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Syvertsen, Guttorm Ernst
(författare)
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Muhammed, MamounKTH,Funktionella material, FNM(Swepub:kth)u1m5r8td
(författare)
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KTHFunktionella material, FNM
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Journal of the Electrochemical Society: The Electrochemical Society156:8, s. K139-K1430013-46511945-7111
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