Toward "Green" Hybrid Materials: Core-Shell Particles with Enhanced Impact Energy Absorbing Ability

Toward "Green" Hybrid Materials : Core-Shell Particles with Enhanced Impact Energy Absorbing Ability

QC 20160915
Restrained properties of "green" degradable products drive the creation of materials with innovative structures and retained eco-attributes. Herein, we introduce the creation of impact modifiers in the form of core-shell (CS) particles toward the creation of "green" composite materials. Particles with CS structure constituted of PLA stereocomplex (PLASC) and a rubbery phase of poly(epsilon-caprolactone-co-D,L-lactide) (P[CL-co-LA]) were successfully achieved by spray droplet atomization. A synergistic association of the soft P[CL-co-LA] and hard PLASC domains in the core-shell structure induced unique thermo-mechanical effects on the PLA-based composites. The core-shell particles enhanced the crystallization of PLA matrices by acting as nucleating agents. The core-shell particles functioned efficiently as impact modifiers with minimal effect on the composites stiffness and strength. These findings provide a new platform for scalable design of polymeric-based structures to be used in the creation of advanced degradable materials.

Odent, Jeremy (författare)
Raquez, Jean-Marie (författare)
Dubois, Philippe (författare)
Odelius, KarinKTH,Fiber- och polymerteknologi(Swepub:kth)u12viu57 (författare)
Albertsson, Ann-ChristineKTH,Fiber- och polymerteknologi(Swepub:kth)u1mpsp3u (författare)
KTHPolymerteknologi (creator_code:org_t)

Ingår i:ACS Sustainable Chemistry and Engineering: American Chemical Society (ACS)4:7, s. 3757-37652168-0485

Av författaren/redakt...: Arias, Veluska; Odent, Jeremy; Raquez, Jean-Mar ...; Dubois, Philippe; Odelius, Karin; Albertsson, Ann- ...

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