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Electrocatalytic wa...
Electrocatalytic water oxidation by a macrocyclic Cu(II) complex in neutral phosphate buffer
- Article/chapterEnglish2016
Publisher, publication year, extent ...
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2016
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Royal Society of Chemistry,2016
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:kth-193261
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-193261URI
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https://doi.org/10.1039/c6cc04884fDOI
Supplementary language notes
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Language:English
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Summary in:English
Part of subdatabase
Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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QC 20161007
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A single-site copper complex, [Cu(TMC)(H2O)](NO3)(2) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was found to be the most active copper-based catalyst towards electrocatalytic water oxidation in neutral aqueous solution. Complex 1 leads to a cathodic shift of approximately 200 mV in potential to reach a current density of 1 mA cm(-2) in comparison with that of the previously reported dinuclear copper complex under the same conditions. Upon immobilization of complex 1 on carbon cloth, it shows greatly improved activity than other copper-based WOCs including CuOx and Cu2+.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Li, Fei
(author)
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Hu, Jixiang
(author)
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Bai, Lichen
(author)
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Zhu, Yong
(author)
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Sun, Licheng,1962-KTH,Kemi(Swepub:kth)u1umfd9h
(author)
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KTHKemi
(creator_code:org_t)
Related titles
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In:Chemical Communications: Royal Society of Chemistry52:68, s. 10377-103801359-73451364-548X
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