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  • Beye, Martin (author)

Chemical Bond Activation Observed with an X-ray Laser

  • Article/chapterEnglish2016

Publisher, publication year, extent ...

  • 2016-09-02
  • American Chemical Society (ACS),2016
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:kth-193994
  • https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-193994URI
  • https://doi.org/10.1021/acs.jpclett.6b01543DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-135185URI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • QC 20161017
  • The concept of bonding and antibonding orbitals is fundamental in chemistry. The population of those orbitals and the energetic difference between the two reflect the strength of the bonding interaction. Weakening the bond is expected to reduce this energetic splitting, but the transient character of bond-activation has so far prohibited direct experimental access. Here we apply time-resolved soft X-ray spectroscopy at a free electron laser to directly observe the decreased bonding antibonding splitting following bond-activation using an ultrashort optical laser pulse.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Öberg, HenrikStockholms universitet,Fysikum(Swepub:su)henrikob (author)
  • Xin, Hongliang (author)
  • Dakovski, Georgi L. (author)
  • Dell'Angela, Martina (author)
  • Foehlisch, Alexander (author)
  • Gladh, JörgenStockholms universitet,Fysikum(Swepub:su)gladh (author)
  • Hantschmann, Markus (author)
  • Hieke, Florian (author)
  • Kaya, Sarp (author)
  • Kuehn, Danilo (author)
  • LaRue, Jerry (author)
  • Pettersson, Lars G. M.Stockholms universitet,Fysikum(Swepub:su)lgm (author)
  • Minitti, Michael P. (author)
  • Mitra, AnkushStockholms universitet,Fysikum (author)
  • Moeller, Stefan P. (author)
  • Ng, May Ling (author)
  • Nilsson, AndersStockholms universitet,Fysikum,SLAC National Accelerator Laboratory, United States(Swepub:su)andersn (author)
  • Nordlund, Dennis (author)
  • Norskov, Jens (author)
  • Östrom, HenrikStockholms universitet,Fysikum(Swepub:su)ostrom (author)
  • Ogasawara, Hirohito (author)
  • Persson, Mats (author)
  • Schlotter, William F. (author)
  • Sellberg, Jonas A.Stockholms universitet,KTH,Biomedicinsk fysik och röntgenfysik,Fysikum,KTH Royal Institute of Technology, Sweden; SLAC National Accelerator Laboratory, United States(Swepub:su)jose4950 (author)
  • Wolf, Martin (author)
  • Abild-Pedersen, Frank (author)
  • Pettersson, Lars G. M. (author)
  • Wurth, Wilfried (author)
  • Stockholms universitetFysikum (creator_code:org_t)

Related titles

  • In:The Journal of Physical Chemistry Letters: American Chemical Society (ACS)7:18, s. 3647-36511948-7185

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