WFRF:(Blomberg Eva)
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- Bergström, L.YKI, Institute for Surface Chemistry (author)
Probing polymeric stabilization in nonaqueous media by direct measurements
- Article/chapterEnglish2000
Publisher, publication year, extent ...
- Wiley,2000
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:kth-19605
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-19605URI
- https://doi.org/10.1111/j.1151-2916.2000.tb01174.xDOI
Supplementary language notes
- Language:English
- Summary in:English
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- SwePubSwePub
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Notes
- QC 20100525 NR 20140804
- The steric repulsion induced by adsorbed layers of the commercial dispersant Hypermer KD3 has been probed by direct measurements in decalin. The forces are long range (commencing at 30-40 nm) and repulsive, and the distance dependence can be modeled with a simple scaling theory expression valid for polymer brushes. We obtain layer thicknesses of similar to 9-15 nm for the compressed layers, depending on KD3 concentration, whereas the undisturbed layers have a thickness of similar to 23-24 nm, independent of polymer concentration. Comparison of the measured interaction lengths with previous layer thickness estimates based on rheological studies shows that the polymer layers are compressed in dense suspensions.
Subject headings and genre
- NATURVETENSKAP Kemi Fysikalisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Physical Chemistry hsv//eng
- rheological properties
- suspensions
- consolidation
- interface
- surfaces
- solvent
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- Blomberg, EvaKTH,Ytkemi(Swepub:kth)u1j8dezr (author)
- YKI, Institute for Surface ChemistryYtkemi (creator_code:org_t)
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- In:Journal of The American Ceramic Society: Wiley83:1, s. 217-2190002-78201551-2916
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