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Graphene Dots Embed...
Graphene Dots Embedded Phosphide Nanosheet-Assembled Tubular Arrays for Efficient and Stable Overall Water Splitting
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Hou, Jungang (author)
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Sun, Yiqing (author)
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Cao, Shuyan (author)
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Wu, Yunzhen (author)
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- Chen, Hong (author)
- KTH,Organisk kemi
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- Sun, Licheng, 1962- (author)
- KTH,Organisk kemi,Molekylär elektronik, CMD,Teoretisk kemi och biologi,Zhejiang-KTH Joint Research Center of Photonics, JORCEP
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(creator_code:org_t)
- 2017-07-14
- 2017
- English.
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In: ACS Applied Materials and Interfaces. - : AMER CHEMICAL SOC. - 1944-8244 .- 1944-8252. ; 9:29, s. 24600-24607
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Bifunctional electrocatalysts are highly desired for overall water splitting. Herein, the design and fabrication of three-dimensional (3D) hierarchical earth-abundant transition bimetallic phosphide arrays constructed by one-dimensional tubular array that was derived from assembling two-dimensional nanosheet framework has been reported by tailoring the Co/Ni ratio and tunable morphologies, and zero-dimensional (0D) graphene dots were embedded on Co-Ni phosphide matrix to construct 0D/2D tubular array as a highly efficient electrode in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). On the basis of advanced merits, such as the high surface-active sites, well-dispersed graphene dots, and enhanced electron transfer capacity as well as the confinement effect of the graphene dots on the nanosheets, the integrated GDs/Co0.8Ni0.2P tubular arrays as anode and cathode exhibit excellent OER and HER performance. By use of GDs/Co0.8Ni0.2 arrays in the two-electrode setup of the device, a remarkable electrocatalytic performance for full water splitting has been achieved with a high current density of 10 mA cm-2 at 1.54 V and outstanding long-term operation stability in an alkaline environment, indicating a promising system based on nonprecious-metal electrocatalysts toward potential practical devices of overall water splitting.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
Keyword
- graphene dots
- transition bimetallic phosphide
- oxygen evolution reaction
- hydrogen evolution reaction
- overall water splitting
Publication and Content Type
- ref (subject category)
- art (subject category)
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