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  • Li, QizhaoEast China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China. (författare)

Regioselectively Halogenated Expanded Porphyrinoids as Building Blocks for Constructing Porphyrin-Porphyrinoid Heterodyads with Tunable Energy Transfer

  • Artikel/kapitelEngelska2019

Förlag, utgivningsår, omfång ...

  • 2019-03-08
  • AMER CHEMICAL SOC,2019
  • printrdacarrier

Nummerbeteckningar

  • LIBRIS-ID:oai:DiVA.org:kth-251206
  • https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-251206URI
  • https://doi.org/10.1021/jacs.8b13148DOI

Kompletterande språkuppgifter

  • Språk:engelska
  • Sammanfattning på:engelska

Ingår i deldatabas

Klassifikation

  • Ämneskategori:ref swepub-contenttype
  • Ämneskategori:art swepub-publicationtype

Anmärkningar

  • QC 20190724
  • Expanded porphyrins have been attracting increasing attention owing to their unique optical and electrochemical properties as well as switchable aromaticity. Toward material applications, regioselective functionalization of the expanded porphyrins at their periphery is indeed challenging due to the presence of multiple reactive sites. Herein, a set of regioselective halogenated isomers (L5-Br-A/B/C) of neo-confused isosmaragdyrin (L5) are synthesized by a combination of the halogenation reaction of L5 and sequential macrocycleto-macrocycle transformation reactions of its halogenated isomers. On this basis, the regioselectively functionalized isosmaragdyrins are utilized as building blocks for constructing multichromophoric porphyrinoids, specifically, heterodyads L5-ZnP-A/B/C, in which a common zinc porphyrin is linked at three different pyrrolic positions of isosmaragdyrins, respectively, by Sonogashira coupling reactions. The highly efficient energy cascade from porphyrin to isosmaragdyrin is elucidated using steady-state/time-resolved spectroscopies and theoretical calculations. Notably, the energy transfer processes from the porphyrin to the isosmaragdyrin moieties as well as the excitation energy transfer rates in L5-ZnP-A/B/C are highly dependent on the linking sites by through-bond and Forster-type resonance energy transfer mechanisms. The site-selective functionalization and subsequent construction of a set of heterodyads of the expanded porphyrinoid would provide opportunities for developing new materials for optoelectronic applications.

Ämnesord och genrebeteckningar

Biuppslag (personer, institutioner, konferenser, titlar ...)

  • Li, ChengjieEast China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China. (författare)
  • Kim, JinseokYonsei Univ, Dept Chem, Seoul 03722, South Korea.;Yonsei Univ, Spect Lab Funct Elect Syst, Seoul 03722, South Korea. (författare)
  • Ishida, MasatoshiKyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka, Fukuoka 8190395, Japan.;Kyushu Univ, Ctr Mol Syst, Fukuoka, Fukuoka 8190395, Japan. (författare)
  • Li, XinKTH,Skolan för kemi, bioteknologi och hälsa (CBH)(Swepub:kth)PI000000 (författare)
  • Gu, TingtingJiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China. (författare)
  • Liang, XuJiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China. (författare)
  • Zhu, WeihuaJiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China. (författare)
  • Ågren, HansKTH,Teoretisk kemi och biologi(Swepub:kth)u1l2s96v (författare)
  • Kim, DonghoYonsei Univ, Dept Chem, Seoul 03722, South Korea.;Yonsei Univ, Spect Lab Funct Elect Syst, Seoul 03722, South Korea. (författare)
  • Furuta, HiroyukiKyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka, Fukuoka 8190395, Japan.;Kyushu Univ, Ctr Mol Syst, Fukuoka, Fukuoka 8190395, Japan. (författare)
  • Xie, YongshuEast China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China. (författare)
  • East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China.Yonsei Univ, Dept Chem, Seoul 03722, South Korea.;Yonsei Univ, Spect Lab Funct Elect Syst, Seoul 03722, South Korea. (creator_code:org_t)

Sammanhörande titlar

  • Ingår i:Journal of the American Chemical Society: AMER CHEMICAL SOC141:13, s. 5294-53020002-78631520-5126

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