WFRF:(Svanström Sebastian)
Sökning: WFRF:(Svanström Sebastian) > (2020) > Degradation Mechani...
- Svanström, SebastianUppsala universitet,Molekyl- och kondenserade materiens fysik (författare)
Degradation Mechanism of Silver Metal Deposited on Lead Halide Perovskites
- Artikel/kapitelEngelska2020
Förlag, utgivningsår, omfång ...
- 2020-01-20
- AMER CHEMICAL SOC,2020
- printrdacarrier
Nummerbeteckningar
- LIBRIS-ID:oai:DiVA.org:kth-269458
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-269458URI
- https://doi.org/10.1021/acsami.9b20315DOI
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-407282URI
Kompletterande språkuppgifter
- Språk:engelska
- Sammanfattning på:engelska
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- SwePubSwePub
Klassifikation
Anmärkningar
- QC 20200310
- Lead halide perovskite solar cells have significantly increased in both efficiency and stability over the last decade. An important aspect of their longterm stability is the reaction between the perovskite and other materials in the solar cell. This includes the contact materials and their degradation if they can potentially come into contact through, e.g., pinholes or material diffusion and migration. Here, we explore the interactions of silver contacts with lead halide perovskites of different compositions by using a model system where thermally evaporated silver was deposited directly on the surface of the perovskites. Using X-ray photoelectron spectroscopy with support from scanning electron microscopy, X-ray diffraction, and UV-visible absorption spectroscopy, we studied the film formation and degradation of silver on perovskites with different compositions. The deposited silver does not form a continuous silver film but instead tends to form particles on a bare perovskite surface. These particles are initially metallic in character but degrade into AgI and AgBr over time. The degradation and migration appear unaffected by the replacement of methylammonium with cesium but are significantly slowed down by the complete replacement of iodide with bromide. The direct contact between silver and the perovskite also significantly accelerates the degradation of the perovskite, with a significant loss of organic cations and the possible formation of PbO, and, at the same time, changed the surface morphology of the iodide-rich perovskite interface. Our results further indicate that an important degradation pathway occurred through gas-phase perovskite degradation products. This highlights the importance of control over the interface materials and the use of completely hermetical barrier layers for the long-term stability and therefore the commercial viability of silver electrodes.
Ämnesord och genrebeteckningar
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- NATURVETENSKAP Kemi Materialkemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Materials Chemistry hsv//eng
- perovskite solar cells
- electrode stability
- X-ray photoelectron spectroscopy
- interface chemistry
- noble metal electrodes
Biuppslag (personer, institutioner, konferenser, titlar ...)
- Jacobsson, Jesper,1984-Uppsala universitet,Fysikalisk kemi(Swepub:uu)jesja828 (författare)
- Boschloo, GerritUppsala universitet,Fysikalisk kemi(Swepub:uu)gerrbosc (författare)
- Johansson, ErikUppsala universitet,Fysikalisk kemi(Swepub:uu)erjoh367 (författare)
- Rensmo, HåkanUppsala universitet,Molekyl- och kondenserade materiens fysik(Swepub:uu)hakanrm (författare)
- Cappel, Ute B.KTH,Tillämpad fysikalisk kemi,KTH Royal Inst Technol, Dept Chem, Div Appl Phys Chem, SE-10044 Stockholm, Sweden(Swepub:kth)u15ztiw5 (författare)
- Uppsala universitetMolekyl- och kondenserade materiens fysik (creator_code:org_t)
Sammanhörande titlar
- Ingår i:ACS Applied Materials and Interfaces: AMER CHEMICAL SOC12:6, s. 7212-72211944-82441944-8252
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- Boschloo, Gerrit
- Johansson, Erik
- Rensmo, Håkan
- Cappel, Ute B.
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