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Anisotropic X-Ray Scattering of Transiently Oriented Water

Kim, Kyung Hwan (author)
Stockholms universitet,Fysikum,POSTECH, Republic of Korea,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.;POSTECH, Dept Chem, Pohang 37673, South Korea.
Späh, Alexander (author)
Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
Pathak, Harshad (author)
Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
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Yang, Cheolhee (author)
POSTECH, Dept Chem, Pohang 37673, South Korea.
Bonetti, Stefano (author)
Stockholms universitet,Fysikum,Ca’ Foscari University of Venice, Italy,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.;Ca Foscari Univ Venice, Dept Mol Sci & Nanosyst, I-30172 Venice, Italy.
Amann-Winkel, Katrin (author)
Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
Mariedahl, Daniel (author)
Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
Schlesinger, Daniel (author)
Stockholms universitet,Fysikum,Institutionen för miljövetenskap,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.;Stockholm Univ, Dept Environm Sci, S-11418 Stockholm, Sweden.;Stockholm Univ, Bolin Ctr Climate Res, S-11418 Stockholm, Sweden.
Sellberg, Jonas A. (author)
KTH,Biomedicinsk fysik och röntgenfysik,Albanova VinnExcellence Center for Protein Technology, ProNova,KTH Royal Inst Technol, AlbaNova Univ Ctr, Dept Appl Phys, Biomed & Xray Phys, S-10691 Stockholm, Sweden.
Mendez, Derek (author)
Lawrence Berkeley Natl Lab, Moleeular Biophys & Integrated Bioimaging Div, Berkeley, CA 94720 USA.
van der Schot, Gijs (author)
Uppsala universitet,Molekylär biofysik
Hwang, Harold Y. (author)
MIT, Dept Chem, Cambridge, MA 02139 USA.
Clark, Jesse (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA.
Shigeki, Owada (author)
Japan Synchrotron Radiat Res Inst, Kouto 1-1-1, Sayo, Hyogo 6795198, Japan.
Tadashi, Togashi (author)
Japan Synchrotron Radiat Res Inst, Kouto 1-1-1, Sayo, Hyogo 6795198, Japan.
Harada, Yoshihisa (author)
Univ Tokyo, Inst Solid State Phys, Kouto 1-1-1, Sayo, Hyogo 6795148, Japan.
Ogasawara, Hirohito (author)
SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA.
Katayama, Tetsuo (author)
Japan Synchrotron Radiat Res Inst, Kouto 1-1-1, Sayo, Hyogo 6795198, Japan.
Nilsson, Anders (author)
Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
Perakis, Fivos (author)
Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
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 (creator_code:org_t)
American Physical Society (APS), 2020
2020
English.
In: Physical Review Letters. - : American Physical Society (APS). - 0031-9007 .- 1079-7114. ; 125:7
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We study the structural dynamics of liquid water by time-resolved anisotropic x-ray scattering under the optical Kerr effect condition. In this way, we can separate the anisotropic scattering decay of 160 fs from the delayed temperature increase of similar to 0.1 K occurring at 1 ps and quantify transient changes in the O-O pair distribution function. Polarizable molecular dynamics simulations reproduce well the experiment, indicating transient alignment of molecules along the electric field, which shortens the nearest-neighbor distances. In addition, analysis of the simulated water local structure provides evidence that two hypothesized fluctuating water configurations exhibit different polarizability.

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences (hsv//eng)
NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

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