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Tailoring of rheolo...
Tailoring of rheological properties and structural polydispersity effects in microfibrillated cellulose suspensions
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- Ciftci, Göksu Cinar (författare)
- KTH,Fiber- och polymerteknologi
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- Larsson, Per A., 1980- (författare)
- KTH,Fiberteknologi
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- Riazanova, Anastasiia (författare)
- KTH,Fiber- och polymerteknologi
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Øvrebø, H.H. (författare)
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- Wågberg, Lars, 1956- (författare)
- KTH,Fiberteknologi
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- Berglund, Lars, 1956- (författare)
- KTH,Fiberteknologi
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(creator_code:org_t)
- 2020-09-16
- 2020
- Engelska.
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Ingår i: Cellulose. - : Springer Science+Business Media B.V.. - 0969-0239 .- 1572-882X. ; 27:16, s. 9227-9241
- Relaterad länk:
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https://doi.org/10.1...
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https://link.springe...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Abstract: Industrial production of low-charge microfibrillated cellulose (MFC) typically results in wide fibril size distributions. This polydispersity influences viscosity, overall colloidal stability, and rheological properties of MFC suspensions and gels in aqueous systems. In this work, a systematic rheological analysis is performed for industrially prepared MFC and fractions of different size distributions. Gel formation and flow characteristics (e.g., shear-thinning) of each fraction are examined under neutral and acidic conditions and compared with the unfractionated MFC suspension. The effects of size, aspect ratio, and surface charge on the rheology of semi-dilute MFC suspensions are discussed. The results demonstrate that particle size and aspect ratio distribution control the viscoelasticity and shear-thinning properties of MFC suspensions. An increased fraction of small diameter nanofibrils, by ex situ addition of the fine particles with high aspect ratio or removal of the coarsest particles (with lower aspect ratio) by fractionation, significantly enhances the storage modulus and the yield stress of the complex mixture, compared to the properties of the coarser fractions. New insights are also reported on the tailoring of the rheology of highly polydisperse fibrillar mixtures, where the rheological contributions of each fraction are discussed. Graphic abstract: [Figure not available: see fulltext.].
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Maskinteknik -- Strömningsmekanik och akustik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Mechanical Engineering -- Fluid Mechanics and Acoustics (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Pappers-, massa- och fiberteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Paper, Pulp and Fiber Technology (hsv//eng)
Nyckelord
- Cellulose nanofibrils
- Gel formation
- Nanocellulose
- Shear-thinning
- Viscoelasticity
- Cellulose
- Cellulose nanocrystals
- Elasticity
- Mixtures
- Non Newtonian flow
- Particle size
- Particle size analysis
- Rheology
- Shear flow
- Shear thinning
- Size distribution
- Suspensions (fluids)
- Yield stress
- Aspect ratio distribution
- Flow charac-teristics
- Industrial production
- Microfibrillated cellulose
- Microfibrillated cellulose (MFC)
- Polydispersity effect
- Rheological analysis
- Rheological property
- Aspect ratio
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