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Thiophene-fused car...
Thiophene-fused carbazole derivative dyes for high-performance dye-sensitized solar cells
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- An, Jincheng (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Yang, Xichuan (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Tian, Zhifeng (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Cai, Bin (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Zhang, Li (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Yu, Ze (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Wang, Xiuna (author)
- Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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- Hagfeldt, Anders (author)
- Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland.
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- Sun, Licheng, 1962- (author)
- KTH,Organisk kemi,Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
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Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, Inst Artificial Photosynth, State Key Lab Fine Chem, Dalian 116024, Peoples R China Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland. (creator_code:org_t)
- Elsevier BV, 2021
- 2021
- English.
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In: Tetrahedron. - : Elsevier BV. - 0040-4020 .- 1464-5416. ; 88
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Two novel dyes that are similar in chemical structure, except for different donor units, AJ301and AJ303 were synthesized, characterized and applied as sensitizers in dye-sensitized solar cells (DSSCs). Both dyes exhibited a wide absorption of visible sunlight. The introduction of fused rings on the donor unit of AJ303 presented an appropriate energy level, less recombination and longer electron lifetime to achieve a power conversion efficiency (PCE) of 10.2%, far above that achieved for AJ301 of 6.2% with a [Co(bpy)(3)](2+/3+)-based electrolyte under standard AM1.5G solar irradiation (100 mW cm(-2)). The DSSCs based on AJ303 and AJ301 with [Cu(tmby)(2)](2+/+)-based electrolyte showed a lower PCE of 8.2% and 5.4%, respectively. Therefore, the results indicated that the introduction of a fused-ring in the donor group is a meaningful synthetic strategy to improve the photovoltaic performance.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Novel carbazole derivative donor
- Dye-sensitized solar cell
- Efficient photovoltaics
- D-pi-A-structured organic sensitizers
- Cobalt electrolyte
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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An, Jincheng
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Yang, Xichuan
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Tian, Zhifeng
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Cai, Bin
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Zhang, Li
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Yu, Ze
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Wang, Xiuna
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Hagfeldt, Anders
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Sun, Licheng, 19 ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
- Articles in the publication
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Tetrahedron
- By the university
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Royal Institute of Technology