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Pyrolysis behaviour...
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Wang, Shule,1994-KTH,Materialvetenskap,KTH Royal Institute of Technology, Sweden
(författare)
Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization-Treated pulp and paper mill sludge
- Artikel/kapitelEngelska2021
Förlag, utgivningsår, omfång ...
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Elsevier BV,2021
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printrdacarrier
Nummerbeteckningar
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LIBRIS-ID:oai:DiVA.org:kth-300016
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-300016URI
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https://doi.org/10.1016/j.renene.2021.06.027DOI
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https://urn.kb.se/resolve?urn=urn:nbn:se:ri:diva-55470URI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:ref swepub-contenttype
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Ämneskategori:art swepub-publicationtype
Anmärkningar
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QC 20210825
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Funding details: China Scholarship Council, CSC; Funding text 1: The authors acknowledge financial support from the FORMAS-Swedish Research Council for Sustainable Development for funding in the frame of the collaborative international consortium (RECOWATDIG) financed under the 2018 Joint call of the WaterWorks2017 ERA-NET Cofund . The authors also greatly acknowledge C-Green AB for the raw materials and information. Cooperation with Envigas AB is highly appreciated. One of the authors, Shule Wang, would also like to acknowledge the Chinese Scholarship Council (CSC) and his girlfriend Q. Hu for the support of this study.
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Organic-rich pulp and paper mill sludge (PPMS) has the potential to become a renewable carbon source for producing alternatives to fossil-based product. In this work, PPMS treated by hydrothermal carbonization (HTC) was investigated based on its pyrolysis properties. The pyrolytic mechanism, kinetics data and product of the sample were studied using TG as well as pyrolysis tests in Py-GC/MS and a bench-scale reactor at 450, 550, and 650 degrees C. The results show that the thermal decomposition of feedstock is a two-stage reaction. The mean activation energy of the pyrolysis of HTC treated PPMS was estimated as 233.08 kl/mol, which is higher than that of the pyrolysis of paper sludge reported before. The changes in enthalpies, entropies and Gibbs free energies from the reactants to the activated complex were estimated. The concentration of monocyclic aromatic hydrocarbons in the derived organic liquid fraction shows a positive correlation with the pyrolysis temperature. At 550 degrees C, the organic liquid fraction reached its highest yield at 13.7% with an oxygen level of 10.7 wt% and a higher heating value of 35.9 MJ/ kg. The pyrolytic chars show that a molar ratio of O:C is less than 0.2, which shows potential for use as a carbon sink.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Wen, YumingKTH,Materialvetenskap,KTH Royal Institute of Technology, Sweden(Swepub:kth)u1pe7rc6
(författare)
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Persson, Henry V.KTH,Materialvetenskap,RISE Res Inst Sweden, Box 5604, SE-11486 Stockholm, Sweden.(Swepub:kth)u1kxcnzu
(författare)
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Jönsson, Pär GöranKTH,Processer,KTH Royal Institute of Technology, Sweden(Swepub:kth)u118w09b
(författare)
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Yang, Weihong,PhD,1968-KTH,Processer,KTH Royal Institute of Technology, Sweden(Swepub:kth)u1cf0tow
(författare)
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Hammarström, HenryRISE,KTH Royal Institute of Technology, Sweden
(författare)
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KTHMaterialvetenskap
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Renewable energy: Elsevier BV177, s. 1282-12920960-14811879-0682
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