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Supramolecular Co-a...
Supramolecular Co-adsorption on TiO2to enhance the efficiency of dye-sensitized solar cells
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An, J. (author)
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Tian, Z. (author)
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Zhang, L. (author)
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Yang, X. (author)
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Cai, B. (author)
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Yu, Z. (author)
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Hagfeldt, A. (author)
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- Sun, Licheng, 1962- (author)
- KTH,Organisk kemi,State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Center on Molecular Devices, Dalian University of Technology (DUT), Dalian 116024, China
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(creator_code:org_t)
- 2021
- 2021
- English.
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In: Journal of Materials Chemistry A. - : Royal Society of Chemistry (RSC). - 2050-7488 .- 2050-7496. ; 9:23, s. 13697-13703
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Three novel push-pull dyes, with carbazole donors, codedAJ502,TZ101andTZ102are synthesized and applied as co-sensitizers in dye-sensitized solar cells (DSSCs).TZ101andTZ102have similar structures except for two fluorine atoms introduced on the benzotriazole (BTZ) unit.AJ502shows a near-IR absorption spectrum that is suitable for co-sensitization withTZ101andTZ102. The co-sensitized DSSC device based onCO-1(AJ502 : TZ101= 3 : 4 (0.075 mM : 0.1 mM)) achieves a power conversion efficiency (PCE) of 10.3% under AM 1.5G irradiation, with 1.06 V open-circuit voltage (Voc), 13.75 mA cm−2short-circuit photocurrent density (Jsc), and 70.8% fill factor (FF), a significant improvement compared to the single dye, 6.0% forAJ502and 5.1% forTZ101with a copper(i/ii)-based redox electrolyte. A PCE of 8.9% is also obtained by devices based onCO-2(AJ502 : TZ102= 3 : 4). ForCO-1, the fluorine atoms inTZ101play a critical role by widening the active light capturing bands of bothTZ101andAJ502on the TiO2film whileTZ102andAJ502show weaker interaction under the same conditions. The UV-vis spectrum and Raman spectrum revealed thatAJ502can form supramolecules withTZ101andTZ102formed on the TiO2film.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Absorption spectroscopy
- Conversion efficiency
- Efficiency
- Electrolytes
- Fluorine
- Open circuit voltage
- Photocurrents
- Carbazole donors
- Co-sensitization
- Light capturing
- Near-IR absorption
- Photocurrent density
- Power conversion efficiencies
- Redox electrolytes
- UV-Vis spectrum
- Dye-sensitized solar cells
Publication and Content Type
- ref (subject category)
- art (subject category)
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