Sökning: WFRF:(Ding Yunxuan) >
Efficient urea elec...
-
Zhao, YilongState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China
(författare)
Efficient urea electrosynthesis from carbon dioxide and nitrate via alternating Cu–W bimetallic C–N coupling sites
- Artikel/kapitelEngelska2023
Förlag, utgivningsår, omfång ...
-
Springer Nature,2023
-
printrdacarrier
Nummerbeteckningar
-
LIBRIS-ID:oai:DiVA.org:kth-335714
-
https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-335714URI
-
https://doi.org/10.1038/s41467-023-40273-2DOI
Kompletterande språkuppgifter
-
Språk:engelska
-
Sammanfattning på:engelska
Ingår i deldatabas
Klassifikation
-
Ämneskategori:ref swepub-contenttype
-
Ämneskategori:art swepub-publicationtype
Anmärkningar
-
QC 20230912
-
Electrocatalytic urea synthesis is an emerging alternative technology to the traditional energy-intensive industrial urea synthesis protocol. Novel strategies are urgently needed to promote the electrocatalytic C–N coupling process and inhibit the side reactions. Here, we report a CuWO4 catalyst with native bimetallic sites that achieves a high urea production rate (98.5 ± 3.2 μg h−1 mg−1cat) for the co-reduction of CO2 and NO3− with a high Faradaic efficiency (70.1 ± 2.4%) at −0.2 V versus the reversible hydrogen electrode. Mechanistic studies demonstrated that the combination of stable intermediates of *NO2 and *CO increases the probability of C–N coupling and reduces the potential barrier, resulting in high Faradaic efficiency and low overpotential. This study provides a new perspective on achieving efficient urea electrosynthesis by stabilizing the key reaction intermediates, which may guide the design of other electrochemical systems for high-value C–N bond-containing chemicals.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
-
Ding, YunxuanCenter of Artificial Photosynthesis for Solar Fuels and Department of Chemistry, School of Science, Westlake University, 310024, Hangzhou, China
(författare)
-
Li, WenlongState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China; Center of Artificial Photosynthesis for Solar Fuels and Department of Chemistry, School of Science, Westlake University, 310024, Hangzhou, China
(författare)
-
Liu, ChangState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China
(författare)
-
Li, YingzhengState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China
(författare)
-
Zhao, ZiqiState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China
(författare)
-
Shan, YuState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China
(författare)
-
Li, FeiState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China
(författare)
-
Sun, Licheng,1962-KTH,Organisk kemi,State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China; Center of Artificial Photosynthesis for Solar Fuels and Department of Chemistry, School of Science, Westlake University, 310024, Hangzhou, China(Swepub:kth)u1umfd9h
(författare)
-
Li, FushengState Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, China(Swepub:kth)u16naruo
(författare)
-
State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116024, Dalian, ChinaCenter of Artificial Photosynthesis for Solar Fuels and Department of Chemistry, School of Science, Westlake University, 310024, Hangzhou, China
(creator_code:org_t)
Sammanhörande titlar
-
Ingår i:Nature Communications: Springer Nature14:12041-1723
Internetlänk
Hitta via bibliotek
Till lärosätets databas
- Av författaren/redakt...
-
Zhao, Yilong
-
Ding, Yunxuan
-
Li, Wenlong
-
Liu, Chang
-
Li, Yingzheng
-
Zhao, Ziqi
-
visa fler...
-
Shan, Yu
-
Li, Fei
-
Sun, Licheng, 19 ...
-
Li, Fusheng
-
visa färre...
- Om ämnet
-
- NATURVETENSKAP
-
NATURVETENSKAP
-
och Kemi
-
och Fysikalisk kemi
- Artiklar i publikationen
-
Nature Communica ...
- Av lärosätet
-
Kungliga Tekniska Högskolan