WFRF:(Kloo L.)
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- Stokes, F.A. (author)
Structure and Bonding of the Manganese(II) Phosphide Complex (t-BuPH(2))(eta(5)-Cp)Mn{mu-(t-BuPH)}(2)Mn(Cp)(t-BuPH(2))
- Article/chapterEnglish2012
Publisher, publication year, extent ...
- 2011-12-19
- American Chemical Society (ACS),2012
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:kth-75574
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-75574URI
- https://doi.org/10.1021/om200381pDOI
Supplementary language notes
- Language:English
- Summary in:English
Part of subdatabase
- SwePubSwePub
Classification
Notes
- QC 20120206
- Rather than achieving bis-deprotonation of the phosphine, reaction of Cp2Mn (Cp = cyclopentadienyl) with t-BuPH2 at room temperature yields monodeprotonation of half of the available phosphine in the product (t-BuPH2)(η5-Cp)Mn{μ-(t-BuPH)}2Mn(Cp)(t-BuPH2) (1). This complex comprises a Mn(II) phosphide and is a dimer in the solid state, containing a Mn2P2 diamond core. Consistent with the observation of a relatively short intermetal distance of 2.8717(4) Å in 1, DFT analysis of the full structure points to a singlet ground state stabilized by a direct Mn–Mn single bond. This is in line with the diamagnetic character of 1 and an 18-electron count at Mn.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- CRYSTAL-STRUCTURES
- DIMANGANESE
- MN
- SUBSTITUTION
- CHEMISTRY
- LIGANDS
- AMIDO
- 1ST
Added entries (persons, corporate bodies, meetings, titles ...)
- Less, R.J. (author)
- Haywood, J. (author)
- Melen, Rebecca L. (author)
- Thompson, R.L. (author)
- Wheatley, A.E. (author)
- Wright, D.S. (author)
- Johansson, Adam JohannesKTH,Fysikalisk kemi(Swepub:kth)u1cyjnbh (author)
- Kloo, LarsKTH,Organisk kemi(Swepub:kth)u1jrdr1m (author)
- KTHFysikalisk kemi (creator_code:org_t)
Related titles
- In:Organometallics: American Chemical Society (ACS)31:1, s. 23-260276-73331520-6041
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- Royal Institute of Technology
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