Iron-silica interaction at extreme conditions and the electrically conducting layer at the base of Earth's mantle

QC 20100624
The boundary between the Earth's metallic core and its silicate mantle is characterized by strong lateral heterogeneity and sharp changes in density, seismic wave velocities, electrical conductivity and chemical composition(1-7). To investigate the composition and properties of the lowermost mantle, an understanding of the chemical reactions that take place between liquid iron and the complex Mg-Fe-Si-Al-oxides of the Earth's lower mantle is first required(8-15). Here we present a study of the interaction between iron and silica (SiO2) in electrically and laser-heated diamond anvil cells. In a multianvil apparatus at pressures up to 140 GPa and temperatures over 3,800 K we simulate conditions down to the core-mantle boundary. At high temperature and pressures below 40 GPa, iron and silica react to form iron oxide and an iron-silicon alloy, with up to 5 wt% silicon. At pressures of 85-140 GPa, however, iron and SiO2 do not react and iron-silicon alloys dissociate into almost pure iron and a CsCl-structured (B2) FeSi compound. Our experiments suggest that a metallic silicon-rich B2 phase, produced at the core-mantle boundary (owing to reactions between iron and silicate(2,9,10,13)), could accumulate at the boundary between the mantle and core and explain the anomalously high electrical conductivity of this region(6).

TEKNIK OCH TEKNOLOGIER Annan teknik Övrig annan teknik hsv//swe
ENGINEERING AND TECHNOLOGY Other Engineering and Technologies Other Engineering and Technologies not elsewhere specified hsv//eng
HIGH-PRESSURE; LIQUID-IRON; INNER-CORE; X-RAY; BOUNDARY; TEMPERATURES; METAL; HETEROGENEITY
Material physics with surface physics
Materialfysik med ytfysik

Dubrovinskaia, N.Bayerisches Geoinstitut, Universität Bayreuth (författare)
Langenhorst, F.Bayerisches Geoinstitut, Universität Bayreuth (författare)
Dobson, D.Bayerisches Geoinstitut, Universität Bayreuth (författare)
Rubie, D.Bayerisches Geoinstitut, Universität Bayreuth (författare)
Gessgmann, C.Max-Planck-Institut für Chemie, Mainz (författare)
Abrikosov, I. A.Condensed Matter Theory Group, Department of Physics, Uppsala University (författare)
Johansson, BörjeKTH,Materialvetenskap(Swepub:kth)u13m8u34 (författare)
Baykov, VitalyKTH,Materialvetenskap (författare)
Vitos, LeventeKTH,Materialvetenskap (författare)
Le Bihan, T.European Synchrotron Radiation Facility, Grenoble (författare)
Crichton, W. A.European Synchrotron Radiation Facility, Grenoble (författare)
Dmitriev, V.Swiss-Norwegian Beam Lines at ESRF, Grenoble (författare)
Weber, H. P.Swiss-Norwegian Beam Lines at ESRF, Grenoble (författare)
Bayerisches Geoinstitut, Universität BayreuthMax-Planck-Institut für Chemie, Mainz (creator_code:org_t)

Ingår i:Nature: Springer Science and Business Media LLC422:6927, s. 58-610028-08361476-4687

Av författaren/redakt...: Dubrovinsky, L.; Dubrovinskaia, N ...; Langenhorst, F.; Dobson, D.; Rubie, D.; Gessgmann, C.; visa fler...; Abrikosov, I. A.; Johansson, Börje; Baykov, Vitaly; Vitos, Levente; Le Bihan, T.; Crichton, W. A.; Dmitriev, V.; Weber, H. P.; visa färre...

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