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Stereoselective Syn...
Stereoselective Synthesis of Polyhydroxyl Surfactants. Stereochemical Influence on Langmuir Monolayers
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- Neimert-Andersson, Kristina (författare)
- KTH,Organisk kemi
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- Blomberg, Eva (författare)
- RISE,KTH,Ytkemi,YKI – Ytkemiska institutet
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- Somfai, Peter (författare)
- KTH,Organisk kemi
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(creator_code:org_t)
- 2004-04-30
- 2004
- Engelska.
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Ingår i: Journal of Organic Chemistry. - : American Chemical Society (ACS). - 0022-3263 .- 1520-6904. ; 69:11, s. 3746-3752
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- Herein is described the synthesis of surfactants featuring polyhydroxylated head groups. Three head groups were prepared via consecutive stereoselective dihydroxylations of a diene. By coupling of these with lipophilic tail groups six novel surfactants have been prepared. The monolayers prepared from four of these have been investigated at the air-water interface. Significant differences were observed between monolayers consisting of enantiomerically pure surfactants contra racemates as well as between diastereomers.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- Interfaces (materials)
- Isomers
- Monolayers
- Stereochemistry
- Synthesis (chemical)
- article
- diastereoisomer
- enantiomer
- hydroxylation
- lipophilicity
- racemic mixture
- stereochemistry
- synthesis
- Organic chemistry
- Organisk kemi
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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