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  • Marion, RonanUniversity of Caen Basse Normandie, France (author)

NHC Copper(I) Complexes Bearing Dipyridylamine Ligands: Synthesis, Structural, and Photoluminescent Studies

  • Article/chapterEnglish2014

Publisher, publication year, extent ...

  • 2014-08-18
  • American Chemical Society,2014
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:liu-111274
  • https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-111274URI
  • https://doi.org/10.1021/ic501230mDOI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • Funding Agencies|Ministere de la Recherche et des Nouvelles Technologies, Centre National de la Recherche Scientifique (CNRS); Agence Nationale de la Recherche [ANR-12-SECU-0002-02]; Region Basse-Normandie; LABEX SynOrg [ANR-11-LABX-0029]; SeRC (Swedish e-Science Research Center)
  • We describe the synthesis of new cationic tricoordinated copper complexes bearing bidentate pyridine-type ligands and N-heterocyclic carbene as ancillary ligands. These cationic copper complexes were fully characterized by NMR, electrochemistry, X-ray analysis, and photophysical studies in different environments. Density functional theory calculations were also undertaken to rationalize the assignment of the electronic structure and the photophysical properties. These tricoordinated cationic copper complexes possess a stabilizing CH-pi interaction leading to high stability in both solid and liquid states. In addition, these copper complexes, bearing dipyridylamine ligands having a central nitrogen atom as potential anchoring point, exhibit very interesting luminescent properties that render them potential candidates for organic light-emitting diode applications.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Sguerra, FabienCEA, France (author)
  • Di Meo, FlorentLinköpings universitet,Beräkningsfysik,Tekniska högskolan(Swepub:liu)flodi20 (author)
  • Sauvageot, ElodieUniversity of Caen Basse Normandie, France (author)
  • Lohier, Jean-FrancoisUniversity of Caen Basse Normandie, France (author)
  • Daniellou, RichardUniversity of Orleans, France (author)
  • Renaud, Jean-LucUniversity of Caen Basse Normandie, France (author)
  • Linares, MathieuLinköpings universitet,Beräkningsfysik,Tekniska högskolan(Swepub:liu)matli20 (author)
  • Hamel, MatthieuCEA, France (author)
  • Gaillard, SylvainUniversity of Caen Basse Normandie, France (author)
  • University of Caen Basse Normandie, FranceCEA, France (creator_code:org_t)

Related titles

  • In:Inorganic Chemistry: American Chemical Society53:17, s. 9181-91910020-16691520-510X

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