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Effects of nitrogen...
Effects of nitrogen vacancies on phase stability and mechanical properties of arc deposited (Ti0.52Al0.48)Ny (y<1) coatings
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- Schramm, Isabella C. (author)
- Linköpings universitet,Nanostrukturerade material,Tekniska fakulteten
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- Pauly, C. (author)
- Functional Materials, Department Materials Science, Saarland University, Saarbrucken, Germany
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- Johansson Jõesaar, Mats P., 1965- (author)
- Linköpings universitet,Nanostrukturerade material,Tekniska fakulteten,SECO Tools AB, Fagersta, Sweden
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- Slawik, S. (author)
- Functional Materials, Department Materials Science, Saarland University, Saarbrucken, Germany
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- Suarez, S. (author)
- Functional Materials, Department Materials Science, Saarland University, Saarbrucken, Germany
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- Mücklich, F. (author)
- Functional Materials, Department Materials Science, Saarland University, Saarbrucken, Germany
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- Odén, Magnus, 1965- (author)
- Linköpings universitet,Nanostrukturerade material,Tekniska fakulteten
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(creator_code:org_t)
- Elsevier, 2017
- 2017
- English.
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In: Surface & Coatings Technology. - : Elsevier. - 0257-8972 .- 1879-3347. ; 330:Supplement C, s. 77-86
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Nitrogen sub-stoichiometric (Ti0.52Al0.48)Ny (0.92 ≥ y ≥ 0.46) coatings were grown in a mixed Ar/N2 atmosphere by cathodic arc deposition on cemented carbide (WC/Co-based) substrates. The coatings present a columnar structure with decreasing column widths from 250 to 60nm, due to a corresponding reduced N content, accompanied by changes in preferred orientation from 200 to 111 to 220. Among these, coatings prepared with 0.92â¥yâ¥0.75 exhibit spinodal decomposition and consequently age hardening at elevated temperatures. A reduced N content upshifts the hardness maximum by >300 °C. For these samples, the high temperature treatment resulted in interdiffusion of substrate elements, Co and C, mainly along column boundaries. Nevertheless, no detrimental effect in the hardness could be correlated. Conversely, a low N content sample (y=0.46) presents significant lattice diffusion of substrate elements Co, C, W, and Ta in the coating. In this case, the substrate elements are present throughout the coating, forming additional phases such as c-Ti(C,N), c-Co(Al,Ti,W), and c-(Ti,W,Ta)(C,N), with an observed increased hardness from 16 to 25GPa. We suggest that the substitution of nitrogen by carbon and the solution of W and Ta in c-TiN are responsible for the observed hardening. Our investigation shows the potential of sub-stoichiometric (Ti1-xAlx)Ny coatings for high temperature applications such as cutting tools and puts forth corresponding criteria for N content selection.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Keyword
- TiAlN
- Thin films
- Nitrogen vacancies
- Spinodal decomposition
- Age hardening
Publication and Content Type
- ref (subject category)
- art (subject category)
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