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Search: (L773:0036 8075 OR L773:1095 9203) lar1:(liu) > (2020-2023) > A piperidinium salt...

A piperidinium salt stabilizes efficient metal-halide perovskite solar cells

Lin, Yen-Hung (author)
Univ Oxford, England
Sakai, Nobuya (author)
Univ Oxford, England
Da, Peimei (author)
Univ Oxford, England
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Wu, Jiaying (author)
Imperial Coll London, England
Sansom, Harry C. (author)
Univ Oxford, England
Ramadan, Alexandra J. (author)
Univ Oxford, England
Mahesh, Suhas (author)
Univ Oxford, England
Liu, Junliang (author)
Univ Oxford, England
Oliver, Robert D. J. (author)
Univ Oxford, England
Lim, Jongchul (author)
Univ Oxford, England; Chungnam Natl Univ, South Korea
Aspitarte, Lee (author)
Oregon State Univ, OR 97331 USA
Sharma, Kshama (author)
Tata Inst Fundamental Res, India
Madhu, P. K. (author)
Tata Inst Fundamental Res, India
Morales-Vilches, Anna B. (author)
Helmholtz Zentrum Berlin Mat & Energie GmbH, Germany
Nayak, Pabitra K. (author)
Univ Oxford, England; Tata Inst Fundamental Res, India
Bai, Sai (author)
Linköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska fakulteten
Gao, Feng (author)
Linköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska fakulteten
Grovenor, Chris R. M. (author)
Univ Oxford, England
Johnston, Michael B. (author)
Univ Oxford, England
Labram, John G. (author)
Oregon State Univ, OR 97331 USA
Durrant, James R. (author)
Imperial Coll London, England; Swansea Univ, Wales
Ball, James M. (author)
Univ Oxford, England
Wenger, Bernard (author)
Univ Oxford, England
Stannowski, Bernd (author)
Helmholtz Zentrum Berlin Mat & Energie GmbH, Germany
Snaith, Henry J. (author)
Univ Oxford, England
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 (creator_code:org_t)
AMER ASSOC ADVANCEMENT SCIENCE, 2020
2020
English.
In: Science. - : AMER ASSOC ADVANCEMENT SCIENCE. - 0036-8075 .- 1095-9203. ; 369:6499, s. 96-
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60 degrees and 85 degrees C, respectively. Our analysis reveals detailed degradation routes that contribute to the failure of aged cells.

Subject headings

MEDICIN OCH HÄLSOVETENSKAP  -- Medicinsk bioteknologi -- Medicinsk bioteknologi (hsv//swe)
MEDICAL AND HEALTH SCIENCES  -- Medical Biotechnology -- Medical Biotechnology (hsv//eng)

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