Electronic-structure investigation of CeB6 by means of soft-x-ray scattering

• The electronic structure of the heavy fermion compound CeB6 is probed by resonant inelastic soft-x-ray scattering using photon energies across the Ce 3d and 4d absorption edges. The hybridization between the localized 4f orbitals and the delocalized valence-band states is studied by identifying the different spectral contributions from inelastic Raman scattering and normal fluorescence. Pronounced energy-loss structures are observed below the elastic peak at both the 3d and 4d thresholds. The origin and character of the inelastic scattering structures are discussed in terms of charge-transfer excitations in connection to the dipole allowed transitions with 4f character. Calculations within the single-impurity Anderson model with full multiplet effects are found to yield consistent spectral functions to the experimental data.

Ämnesord

NATURVETENSKAP  -- Fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Nyckelord

NATURAL SCIENCES

NATURVETENSKAP

RARE-EARTH HEXABORIDES; HIGH-RESOLUTION; PHOTOEMISSION SPECTROSCOPY; RESONANT PHOTOEMISSION; EMISSION SPECTRA; SINGLE-CRYSTALS; SYSTEMS; EXCITATIONS; SURFACE; CERIUM

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