Organic-Inorganic Hybrid Films of the Sulfate Dawson Polyoxometalate, [S2W18O62]4-, and Polypyrrole for Iodate Electrocatalysis

• The Dawson-type sulfate polyoxometalate (POM) [S2W18O62]4- has successfully been entrapped in polypyrrole (PPy) films on glassy carbon electrode (GCE) surfaces through pyrrole electropolymerization. Films of varying POM loadings (i.e., thickness) were grown by chronocoulometry. Film-coated electrodes were then characterized using voltammetry, revealing POM surface coverages ranging from 1.9 to 11.7 x 10-9 mol center dot cm-2, and were stable over 100 redox cycles. Typical film morphology and composition were revealed to be porous using atomic force microscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy, and the effects of this porosity on POM redox activity were probed using AC impedance. The hybrid organic- inorganic films exhibited a good electrocatalytic response toward the reduction of iodate with a sensitivity of 0.769 mu A center dot cm-2 center dot mu M-1.

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NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

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