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  • Gangaprasad Rao, SmitaLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, S-58183 Linköping, Sweden. (author)

Phase formation in CrFeCoNi nitride thin films

  • Article/chapterEnglish2023

Publisher, publication year, extent ...

  • AMER PHYSICAL SOC,2023
  • electronicrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:liu-195786
  • https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-195786URI
  • https://doi.org/10.1103/PhysRevMaterials.7.055002DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-506584URI

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  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • Funding Agencies|VINNOVA Competence Centre FunMat-II [2016-05156]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009 00971]; Knut and Alice Wallenberg foundation through the Wallenberg Academy Fellows program [KAW-2020.0196]; Wallenberg Scholar Grant [KAW-2018.0194]; Swedish Foundation for Strategic research [SSF-FFL 15-0290]; Swedish Research Council (VR) [2019-05403, 2021-03826]; Swedish Research Council [2018-05973]; Swedish Research Council VR-RFI [2019-00191]; Swedish Foundation for Strategic Research [2021-00171, RIF21-0026]
  • As a single-phase alloy, CrFeCoNi is a face centered cubic (fcc) material related to the archetypical highentropy Cantor alloy CrFeCoNiMn. For thin films, CrFeCoNi of approximately equimolar composition tends to assume an fcc structure when grown at room temperature by magnetron sputtering. However, the single-phase solid solution state is typically not achieved for thin films grown at higher temperatures. The same holds true for Cantor alloy-based ceramics (nitrides and oxides), where phase formation is extremely sensitive to process parameters such as the amount of reactive gas. This study combines theoretical and experimental methods to understand the phase formation in nitrogen-containing CrFeCoNi thin films. Density functional theory calculations considering three competing phases (CrN, Fe-Ni and Co) show that the free energy of mixing, Delta G of (CrFeCoNi)(1-x)N-x solid solutions has a maximum at x = 0.20-0.25, and AG becomes lower when x < 0.20 and x > 0.25. Thin films of (CrFeCoNi)1-xNx (0.14 >= x <= 0.41) grown by magnetron sputtering show stabilization of the metallic fcc when x <= 0.22 and the stabilization of the NaCl B1 structure when x > 0.33, consistent with the theoretical prediction. In contrast, films with intermediate amounts of nitrogen (x = 0.22) grown at higher temperatures show segregation into multiple phases of CrN, Fe-Ni-rich and Co. These results offer an explanation for the requirement of kinetically limited growth conditions at low temperature for obtaining single-phase CrFeCoNi Cantor-like nitrogen-containing thin films and are of importance for understanding the phase-formation mechanisms in multicomponent ceramics. The results from the study further aid in making correlations between the observed mechanical properties and the crystal structure of the films.

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  • Mukhamedov, BoburjonLinköpings universitet,Teoretisk Fysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Theoret Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)bobmu63 (author)
  • Nagy, GyulaUppsala universitet,Tillämpad kärnfysik,Uppsala Univ, Sweden(Swepub:uu)gyuna995 (author)
  • Tseng, Eric NestorLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)erine87 (author)
  • Shu, RuiLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)ruish16 (author)
  • Boyd, Robert,1972-Linköpings universitet,Plasma och ytbeläggningsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Plasma & Coatings Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)robbo87 (author)
  • Primetzhofer, DanielUppsala universitet,Tillämpad kärnfysik,Uppsala Univ, Sweden(Swepub:uu)danpr521 (author)
  • Persson, Per O ALinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)perpe25 (author)
  • Alling, BjörnLinköpings universitet,Teoretisk Fysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Theoret Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)bjoal69 (author)
  • Abrikosov, IgorLinköpings universitet,Teoretisk Fysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Theoret Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)igoab43 (author)
  • Le Febvrier, ArnaudLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)arnle40 (author)
  • Eklund, PerLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Linköping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, S-58183 Linköping, Sweden.(Swepub:liu)perek02 (author)
  • Linköpings universitetTunnfilmsfysik (creator_code:org_t)

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  • In:Physical Review Materials: AMER PHYSICAL SOC7:42475-9953

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