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Bismuth-Based Perov...
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Trifiletti, VaniraUniv Milano Bicocca, Italy; Univ Milano Bicocca, Italy; Queen Mary Univ London, England
(författare)
Bismuth-Based Perovskite Derivates with Thermal Voltage Exceeding 40 mV/K
- Artikel/kapitelEngelska2024
Förlag, utgivningsår, omfång ...
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2024
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AMER CHEMICAL SOC,2024
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printrdacarrier
Nummerbeteckningar
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LIBRIS-ID:oai:DiVA.org:liu-202245
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-202245URI
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https://doi.org/10.1021/acs.jpcc.3c06324DOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:ref swepub-contenttype
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Ämneskategori:art swepub-publicationtype
Anmärkningar
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Funding Agencies|H2020 Marie Sklodowska-Curie Actions [56338]; European Union [IESR3193231]; Royal Society International Exchanges Award; Fondo di Ateneo Quota Competitiva [2023-ATEQC-0078]; Innovate UK; National Recovery and Resilience Plan (NRRP) Mission 4 Component 2 Investment Line 1.5 [UF140372, URF/R/201013]
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Heat is an inexhaustible source of energy, and it can be exploited by thermoelectronics to produce electrical power or electrical responses. The search for a low-cost thermoelectric material that could achieve high efficiencies and can also be straightforwardly scalable has turned significant attention to the halide perovskite family. Here, we report the thermal voltage response of bismuth-based perovskite derivates and suggest a path to increase the electrical conductivity by applying chalcogenide doping. The films were produced by drop-casting or spin coating, and sulfur was introduced in the precursor solution using bismuth triethylxanthate. The physical-chemical analysis confirms the substitution. The sulfur introduction caused resistivity reduction by 2 orders of magnitude, and the thermal voltage exceeded 40 mV K-1 near 300 K in doped and undoped bismuth-based perovskite derivates. X-ray diffraction, Raman spectroscopy, and grazing-incidence wide-angle X-ray scattering were employed to confirm the structure. X-ray photoelectron spectroscopy, elemental analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were employed to study the composition and morphology of the produced thin films. UV-visible absorbance, photoluminescence, inverse photoemission, and ultraviolet photoelectron spectroscopies have been used to investigate the energy band gap.
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Biuppslag (personer, institutioner, konferenser, titlar ...)
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Massetti, MatteoLinköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten(Swepub:liu)matma26
(författare)
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Calloni, AlbertoPolitecn Milan, Italy
(författare)
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Luong, SallyQueen Mary Univ London, England
(författare)
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Pianetti, AndreaUniv Milano Bicocca, Italy; Univ Milano Bicocca, Italy
(författare)
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Milita, SilviaInst Microelect & Microsyst CNRIMM, Italy
(författare)
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Schroeder, Bob C.Univ London, England
(författare)
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Bussetti, GianlorenzoPolitecn Milan, Italy
(författare)
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Binetti, SimonaUniv Milano Bicocca, Italy; Univ Milano Bicocca, Italy
(författare)
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Fabiano, SimoneLinköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten(Swepub:liu)simfa84
(författare)
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Fenwick, OliverQueen Mary Univ London, England
(författare)
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Univ Milano Bicocca, Italy; Univ Milano Bicocca, Italy; Queen Mary Univ London, EnglandLaboratoriet för organisk elektronik
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:The Journal of Physical Chemistry C: AMER CHEMICAL SOC1932-74471932-7455
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Trifiletti, Vani ...
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Massetti, Matteo
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Calloni, Alberto
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Luong, Sally
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Pianetti, Andrea
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Milita, Silvia
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visa fler...
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Schroeder, Bob C ...
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Bussetti, Gianlo ...
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Binetti, Simona
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Fabiano, Simone
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Fenwick, Oliver
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visa färre...
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