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  • Wang, L.-L.Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 West Green Street, Urbana, IL 61801, United States, Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States (author)

Origin of bulklike structure and bond length disorder of Pt37 and Pt6Ru31 clusters on carbon : Comparison of theory and experiment

  • Article/chapterEnglish2006

Publisher, publication year, extent ...

  • 2005-12-10
  • American Chemical Society (ACS),2006
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:liu-50314
  • https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-50314URI
  • https://doi.org/10.1021/ja053896mDOI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • We describe a theoretical analysis of the structures of self-organizing nanoparticles formed by Pt and Ru-Pt on carbon support. The calculations provide insights into the nature of these metal particle systems-ones of current interest for use as the electrocatalytic materials of direct oxidation fuel cells- and clarify complex behaviors noted in earlier experimental studies. With clusters deposited via metalloorganic Pt or PtRu5 complexes, previous experiments [Nashner et al. J. Am. Chem. Soc. 1997, 119, 7760, Nashner et al. J. Am. Chem. Soc. 1998, 120, 8093, Frenkel et al. J. Phys. Chem. B 2001, 105, 12689] showed that the Pt and Pt-Ru based clusters are formed with fcc(111)-stacked cuboctahedral geometry and essentially bulklike metal-metal bond lengths, even for the smallest (few atom) nanoparticles for which the average coordination number is much smaller than that in the bulk, and that Pt in bimetallic [PtRu5] clusters segregates to the ambient surface of the supported nanoparticles. We explain these observations and characterize the cluster structures and bond length distributions using density functional theory calculations with graphite as a model for the support. The present study reveals the origin of the observed metal-metal bond length disorder, distinctively different for each system, and demonstrates the profound consequences that result from the cluster/carbon-support interactions and their key role in the structure and electronic properties of supported metallic nanoparticles. © 2006 American Chemical Society.

Subject headings and genre

  • TECHNOLOGY
  • TEKNIKVETENSKAP

Added entries (persons, corporate bodies, meetings, titles ...)

  • Khare, S.V.Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 West Green Street, Urbana, IL 61801, United States, Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States, Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606, United States (author)
  • Chirita, ValeriuLinköpings universitet,Tekniska högskolan,Tunnfilmsfysik(Swepub:liu)valch35 (author)
  • Johnson, D.D.Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 West Green Street, Urbana, IL 61801, United States, Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States (author)
  • Rockett, A.A.Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 West Green Street, Urbana, IL 61801, United States, Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States (author)
  • Frenkel, A.I.Department of Physics, Yeshiva University, New York, NY 10016, United States (author)
  • Mack, N.H.Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States, Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, United States (author)
  • Nuzzo, R.G.Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States, Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, United States (author)
  • Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 West Green Street, Urbana, IL 61801, United States, Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United StatesDepartment of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 West Green Street, Urbana, IL 61801, United States, Frederick Seitz Materials Research Laboratory, 104 South Goodwin Avenue, Urbana, IL 61801, United States, Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606, United States (creator_code:org_t)

Related titles

  • In:Journal of the American Chemical Society: American Chemical Society (ACS)128:1, s. 131-1420002-78631520-5126

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