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Molecular ordering ...
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Doherty, Walter JUniversity of Arizona
(author)
Molecular ordering in monolayers of an alkyl-Substituted perylene-bisimide dye by attenuated total reflectance ultraviolet-visible spectroscopy
- Article/chapterEnglish2005
Publisher, publication year, extent ...
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2016-08-31
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SAGE Publications,2005
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:liu-50418
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-50418URI
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https://doi.org/10.1366/000370205774430918DOI
Supplementary language notes
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Language:English
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Summary in:English
Part of subdatabase
Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Surface-relative orientational parameters were determined for monolayer films of N, N'-ditridecylperylenetetracarboxylic dianhydridediimide (C 13-PTCDI) in terms of the relative electronic transition dipole strengths, providing a three-dimensional view of the absorption dipole distribution. In order to obtain a macroscopically ordered film, C 13-PTCDI was deposited by (1) horizontal Langmuir-Blodgett (LB) transfer onto methyl- and phenyl-silanized glass, and (2) vapor deposition onto oriented films of poly(tetrafluoroethylene) (PTFE) on glass. Films of LB-deposited C13-PTCDI were found to be completely Isotropic prior to annealing. After annealing, these films remained isotropic in the plane of the substrate while the out-of-plane anisotropy was significantly enhanced. In contrast, films of C13-PTCDI vapor deposited onto oriented poly(tetrafluoroethylene) (PTFE)-modified substrates yielded films with a high degree of both in- and out-of-plane anisotropy. Atomic force microscopy (AFM) images of both the LB- and vapor-deposited films show substantial differences in film morphology and long-range order. These results demonstrate that molecular orientation in C13-PTCDI films can be controlled by varying substrate surface chemistry and post-deposition processing. © 2005 Society for Applied Spectroscopy.
Subject headings and genre
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ATR
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Attenuated total reflection
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Molecular orientation
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Perylene
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TECHNOLOGY
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TEKNIKVETENSKAP
Added entries (persons, corporate bodies, meetings, titles ...)
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Simmonds, A.G.Department of Chemistry, University of Arizona, Tucson, AZ 85721
(author)
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Mendes, S.B.Department of Chemistry, University of Arizona, Tucson, AZ 85721, Optical Sciences Center, University of Arizona, Tucson, AZ 85721
(author)
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Armstrong, N.R.Department of Chemistry, University of Arizona, Tucson, AZ 85721, Optical Sciences Center, University of Arizona, Tucson, AZ 85721
(author)
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Saavedra, S.S.Department of Chemistry, University of Arizona, Tucson, AZ 85721
(author)
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University of ArizonaDepartment of Chemistry, University of Arizona, Tucson, AZ 85721
(creator_code:org_t)
Related titles
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In:Applied Spectroscopy: SAGE Publications59:10, s. 1248-12560003-70281943-3530
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