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Methanol induced hy...
Methanol induced hydrogen permeation through a Pd membrane
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- Amandusson, Helena (author)
- Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska högskolan
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- Ekedahl, Lars-Gunnar (author)
- Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska högskolan
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- Dannetun, Helen, 1957- (author)
- Linköpings universitet,Tillämpad Fysik,Tekniska högskolan
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(creator_code:org_t)
- 1999
- 1999
- English.
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In: Surface Science. - 0039-6028 .- 1879-2758. ; 442:2, s. 199-205
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- The dehydrogenation of methanol and the subsequent permeation of hydrogen through a 25 μm thick palladium film has been studied in a catalytic membrane reactor. At the temperature studied, 350°C, the decomposition pathway for methanol on clean palladium surfaces is believed to lead to Had and a carbonaceous overlayer. The released hydrogen can either desorb or permeate the palladium membrane. During a continuous supply of methanol hydrogen permeation is reduced and, eventually, totally quenched by the growing carbon monoxide/carbon coverage. Adding oxygen in the methanol supply can balance the increasing carbonaceous coverage through the production of carbon dioxide. In such a case, it is concluded that no CO bond scission occurs. The methanol/oxygen ratio is crucial for the hydrogen permeation rate. Isotope-labelled methanol, CH3OH, CH3OD, CD3OH and CD3OD, shows that it is preferentially the methyl (or methoxy) hydrogen that permeates the membrane.
Keyword
- TECHNOLOGY
- TEKNIKVETENSKAP
Publication and Content Type
- ref (subject category)
- art (subject category)
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