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Two novel two-photon polymerization initiators with extensive application prospects

Tian, Yupeng (author)
Department of Chemistry, Anhui university, China
Zhang, Mingliang (author)
Department of Chemistry, Anhui university, China
Yu, Xiaoqiang (author)
State Key Laboratory of Crystal Materials, Shandong University, China
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Xu, Guibao (author)
State Key Laboratory of Crystal Materials, Shandong University, China
Ren, Yan (author)
State Key Laboratory of Crystal Materials, Shandong University, China
Yang, Jiaxiang (author)
State Key Laboratory of Crystal Materials, Shandong University, China
Wu, Jieying (author)
Department of Chemistry, Anhui university, China
Zhang, Xuanjun (author)
Department of Chemistry, Anhui university, China
Tao, Xutang (author)
State Key Laboratory of Crystal Materials, Shandong University, China
Zhang, Shengyi (author)
Department of Chemistry, Anhui university, China
Jiang, Minhua (author)
State Key Laboratory of Crystal Materials, Shandong University, China
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 (creator_code:org_t)
Elsevier, 2004
2004
English.
In: Chemical Physics Letters. - : Elsevier. - 0009-2614 .- 1873-4448. ; 388:4-6, s. 325-329
Related links:
https://urn.kb.se/re...
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https://doi.org/10.1...
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  • Journal article (peer-reviewed)
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  • Two novel two-photon polymerization initiators, 10-ethyl-3-E-(4-(N,N′-di-n-butylamino)styryl)phenothiazine 5 and 10-ethyl-3,7-E,E-bis(4-(N,N′-di-n-butyl amino)styryl)phenothiazine 6, have been efficiently synthesized with room temperature solid phase Wittig reaction. Two initiators were found to exhibit good single-photon fluorescence emission and their quantum yields, lifetimes and solvent effects have been studied in detail. Two-photon fluorescence spectra were investigated under 800 nm fs laser pulse and two-photon absorption (TPA) cross-sections of the initiators have been evaluated by theoretical calculation.Two-photon initiating polymerization microfabrication experiments have been carried out and artificial defects were made and polymerization mechanism was also discussed.

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