Zn(II) and Cd(II) N-carbazolylacetates with strong fluorescence

• N-carbazolylacetic acid was synthesized using a new method in a high yield and two carbazolylacetato complexes [Zn(Cabo)-(phen)2ClO4]·0.5C2H5OH and [Cd(Cabo)(phen)2-ClO4] (Cabo=N-carbazolylacetate, phen=1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, UV–Vis spectra, thermal analyses, photoluminescence measurement and X-ray diffraction studies. Both of the complexes exhibit strong blue emission in solid state as well as high thermal stability and solvent-resistant properties.

Nyckelord

Carbazole; N-carbazolylacetate; Crystal structures; Complexes; Photoluminescence

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