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Simple directed mat...
Simple directed material design through in situ substitution of proton with Cu+ ions
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- Bo, Qi-Bing (författare)
- Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China
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- Sun, Zhong-Xi (författare)
- Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China
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- Sun, Guo-Xin (författare)
- Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China
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visa fler...
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- Holmgren, Allan (författare)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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Institute of Chemistry and Chemical Engineering, University of Jinan, No106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China Industriell miljö- och processteknik (creator_code:org_t)
- 2009-06-09
- 2009
- Engelska.
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Ingår i: Journal of Inorganic and Organometallic Polymers and Materials. - : Springer Science and Business Media LLC. - 1574-1443 .- 1574-1451. ; 19:4, s. 485-493
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A new inorganic-organic hybrid material (C10H8N2H)2(Mo8O26) · 2NH4 (1) was prepared under solvothermal conditions (H2O/ethanol), which was then used as a starting material in the synthesis of another material, (C10H8N2Cu)2(Mo8O26) · 2NH4 (2). Each compound has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, thermogravimetric analysis, fluorescence, FT-IR, and bond valence sum calculations. The comparative study focuses on the transformation and structural change between 1 and 2, which arises from the simple substitution of the proton in 1 with the Cu+ ions. The other surprising feature is that Cu+ ions can not only directly be used to substitute the proton of 1 but also ameliorate its photoluminescence property. It means that 1 appears to have recognizable functional protons in the solid-state structure and, hence, can very well be considered as an ideal precursor agent to design the functional materials with special architectures and photoactive properties.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- Chemistry of Interfaces
- Gränsytors kemi
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