Simple directed material design through in situ substitution of proton with Cu+ ions

Bo, Qi-BingInstitute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China (author)

Validerad; 2009; 20090702 (ysko)
A new inorganic-organic hybrid material (C10H8N2H)2(Mo8O26) · 2NH4 (1) was prepared under solvothermal conditions (H2O/ethanol), which was then used as a starting material in the synthesis of another material, (C10H8N2Cu)2(Mo8O26) · 2NH4 (2). Each compound has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, thermogravimetric analysis, fluorescence, FT-IR, and bond valence sum calculations. The comparative study focuses on the transformation and structural change between 1 and 2, which arises from the simple substitution of the proton in 1 with the Cu+ ions. The other surprising feature is that Cu+ ions can not only directly be used to substitute the proton of 1 but also ameliorate its photoluminescence property. It means that 1 appears to have recognizable functional protons in the solid-state structure and, hence, can very well be considered as an ideal precursor agent to design the functional materials with special architectures and photoactive properties.

Sun, Zhong-XiInstitute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China (author)
Sun, Guo-XinInstitute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China (author)
Holmgren, AllanLuleå tekniska universitet,Industriell miljö- och processteknik(Swepub:ltu)alho (author)
Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of ChinaIndustriell miljö- och processteknik (creator_code:org_t)

In:Journal of Inorganic and Organometallic Polymers and Materials: Springer Science and Business Media LLC19:4, s. 485-4931574-14431574-1451

By the author/editor: Bo, Qi-Bing; Sun, Zhong-Xi; Sun, Guo-Xin; Holmgren, Allan

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NATURAL SCIENCES: NATURAL SCIENCES; and Chemical Science ...; and Physical Chemist ...

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