Reactivity of CO2 with aqueous choline-based ionic liquids probed by solid-state NMR spectroscopy

Filippov, Andrei,PhD,1957-Luleå tekniska universitet,Kemiteknik,Kazan State Medical University, Kazan, Russia (författare)

Validerad;2019;Nivå 2;2019-05-14 (johcin)
CO2 absorption in a series of choline-based ionic liquids is investigated using solid-state 13C and 15N MAS NMR spectroscopy. Natural abundance and 13C enriched CO2 gas was purged through 50 wt% aqueous solutions of alkyldimethyl(2-hydroxyethyl)ammonium threonine, [N1,1,n,2OH][Threo], (alkyl = butyl, pentyl and hexyl) and pentyldimethyl(2-hydroxyethyl)ammonium taurine [N1,1,5,2OH][Tau]. The process of CO2 absorption results in precipitation of a solid sediment, which stays in equilibrium with the liquid phase. Upon degassing of the sample, the sediment is dissolved back into the IL-aqueous phase. Solid state 13C and 15N MAS NMR data suggest that the solid sediment is composed of neutral threonine (or taurine) in the zwitterionic forms and the liquid phase contained the products of reactions between the ionic liquids and CO2 molecules. A plausible mechanism for formation of the solid sediments and the reaction products in liquid phases is suggested.

Antzutkin, OlegLuleå tekniska universitet,Kemiteknik,Department of Physics, Warwick University, Coventry, UK(Swepub:ltu)olan (författare)
Shah, Faiz Ullah,1981-Luleå tekniska universitet,Kemiteknik(Swepub:ltu)faisha (författare)
Luleå tekniska universitetKemiteknik (creator_code:org_t)

Av författaren/redakt...: Filippov, Andrei ...; Antzutkin, Oleg; Shah, Faiz Ullah ...

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