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  • Galvez-Martinez, SantosCentro de Astrobiología (CSIC-INTA), Madrid, Spain (author)

Defects on a pyrite(100) surface produce chemical evolution of glycine under inert conditions : experimental and theoretical approaches

  • Article/chapterEnglish2019

Publisher, publication year, extent ...

  • Royal Society of Chemistry,2019
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:ltu-76380
  • https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-76380URI
  • https://doi.org/10.1039/C9CP03577JDOI

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  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • Validerad;2019;Nivå 2;2019-12-09 (johcin)
  • The presence of non-stoichiometric sites on the pyrite(100) surface makes it a suitable substrate for driving the chemical evolution of the amino acid glycine over time, even under inert conditions. Spectroscopic molecular fingerprints prove a transition process from a zwitterionic species to an anionic species over time on the monosulfide enriched surface. By combining experimental and theoretical approaches, we propose a surface mechanism where the interaction between the amino acid species and the surface will be driven by the quenching of the surface states at Fe sites and favoured by sulfur vacancies. This study demonstrates the potential capability of pyrite to act as a surface catalyst.

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  • Escamilla-Roa, ElizabethLuleå tekniska universitet,Rymdteknik(Swepub:ltu)eliesc (author)
  • Zorzano Mier, María-PazLuleå tekniska universitet,Rymdteknik,Centro de Astrobiología (CSIC-INTA), Madrid, Spain(Swepub:ltu)marzor (author)
  • Mateo-Marti, E.Centro de Astrobiología (CSIC-INTA), Madrid, Spain (author)
  • Centro de Astrobiología (CSIC-INTA), Madrid, SpainRymdteknik (creator_code:org_t)

Related titles

  • In:Physical Chemistry, Chemical Physics - PCCP: Royal Society of Chemistry21:44, s. 24535-245421463-90761463-9084

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