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  • Wang, Yong-LeiStockholms universitet,Institutionen för material- och miljökemi (MMK),Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden (författare)

Microstructural and Dynamical Heterogeneities in Ionic Liquids

  • Artikel/kapitelEngelska2020

Förlag, utgivningsår, omfång ...

  • 2020-04-15
  • American Chemical Society (ACS),2020
  • printrdacarrier

Nummerbeteckningar

  • LIBRIS-ID:oai:DiVA.org:ltu-78709
  • https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-78709URI
  • https://doi.org/10.1021/acs.chemrev.9b00693DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-184504URI

Kompletterande språkuppgifter

  • Språk:engelska
  • Sammanfattning på:engelska

Ingår i deldatabas

Klassifikation

  • Ämneskategori:ref swepub-contenttype
  • Ämneskategori:for swepub-publicationtype

Anmärkningar

  • Validerad;2020;Nivå 2;2020-08-19 (johcin)
  • Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied molecular symmetry and charge delocalization. The versatility in combining varied cation–anion moieties and in functionalizing ions with different atoms and molecular groups contributes to their peculiar interactions ranging from weak isotropic associations to strong, specific, and anisotropic forces. A delicate interplay among intra- and intermolecular interactions facilitates the formation of heterogeneous microstructures and liquid morphologies, which further contributes to their striking dynamical properties. Microstructural and dynamical heterogeneities of ILs lead to their multifaceted properties described by an inherent designer feature, which makes ILs important candidates for novel solvents, electrolytes, and functional materials in academia and industrial applications. Due to a massive number of combinations of ion pairs with ion species having distinct molecular structures and IL mixtures containing varied molecular solvents, a comprehensive understanding of their hierarchical structural and dynamical quantities is of great significance for a rational selection of ILs with appropriate properties and thereafter advancing their macroscopic functionalities in applications. In this review, we comprehensively trace recent advances in understanding delicate interplay of strong and weak interactions that underpin their complex phase behaviors with a particular emphasis on understanding heterogeneous microstructures and dynamics of ILs in bulk liquids, in mixtures with cosolvents, and in interfacial regions.

Ämnesord och genrebeteckningar

Biuppslag (personer, institutioner, konferenser, titlar ...)

  • Li, BinSchool of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, P. R. China (författare)
  • Sarman, StenStockholms universitet,Institutionen för material- och miljökemi (MMK),Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden(Swepub:su)ssarm (författare)
  • Mocci, FrancescaDepartment of Chemical and Geological Sciences, University of Cagliari, I-09042 Monserrato, Italy (författare)
  • Lu, Zhong-YuanState Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, Jilin University, Changchun 130021, P. R. China (författare)
  • Yuan, JiayinStockholms universitet,Institutionen för material- och miljökemi (MMK),Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden(Swepub:su)jiyu0266 (författare)
  • Laaksonen, AattoStockholms universitet,Luleå tekniska universitet,Energivetenskap,Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden. State Key Laboratory of Materials-Oriented and Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China. Centre of Advanced Research in Bionanoconjugates and Biopolymers, Petru Poni Institute of Macromolecular Chemistry, 700487 Iasi, Romania,Institutionen för material- och miljökemi (MMK),Nanjing Tech University, P. R. China; Petru Poni Institute of Macromolecular Chemistry, Romania; Luleå University of Technology, Sweden(Swepub:su)aatto (författare)
  • Fayer, Michael D.Department of Chemistry, Stanford University, Stanford, California 94305, United States (författare)
  • Stockholms universitetInstitutionen för material- och miljökemi (MMK) (creator_code:org_t)

Sammanhörande titlar

  • Ingår i:Chemical Reviews: American Chemical Society (ACS)120:13, s. 5798-58770009-26651520-6890

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