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An Intrinsic Self-C...
An Intrinsic Self-Charging Biosupercapacitor Comprised of a High-Potential Bioanode and a Low-Potential Biocathode
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- Alsaoub, Sabine (författare)
- Analytical Chemistry-Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, Universitätstrasse 150, 44780, Bochum, Germany
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- Ruff, Adrian (författare)
- Analytical Chemistry-Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, Universitätstrasse 150, 44780, Bochum, Germany
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- Conzuelo, Felipe (författare)
- Analytical Chemistry-Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, Universitätstrasse 150, 44780, Bochum, Germany
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- Ventosa, Edgar (författare)
- Analytical Chemistry-Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, Universitätstrasse 150, 44780, Bochum, Germany
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- Ludwig, Roland (författare)
- Department of Food Sciences and Technology, Vienna Institute of Biotechnology, BOKU-University of Natural Resources and Life Sciences, Muthgasse 11/1/56, 1190, Vienna, Austria
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- Shleev, Sergey (författare)
- Malmö högskola,Institutionen för biomedicinsk vetenskap (BMV),Biofilms Research Center for Biointerfaces,Kurchatov's Complex of NBICS-technologies, National Research Center "Kurchatov Institute", Akademika Kurchatova Sq. 1, 123 182, Moscow, Russia
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- Schuhmann, Wolfgang (författare)
- Analytical Chemistry-Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, Universitätstrasse 150, 44780, Bochum, Germany
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(creator_code:org_t)
- 2017-03-31
- 2017
- Engelska.
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Ingår i: ChemPlusChem. - : John Wiley & Sons. - 2192-6506. ; 82:4, s. 576-583
- Relaterad länk:
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http://rdcu.be/wtXm/
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- An intrinsic self-charging biosupercapacitor built on a unique concept for the fabrication of biodevices based on redox polymers is presented. The biosupercapacitor consists of a high-potential redox polymer based bioanode and a low-potential redox polymer based biocathode in which the potentials of the electrodes in the discharged state show an apparent potential mismatch E-anode > E-cathode and prevent the use of the device as a conventional biofuel cell. Upon charging, the potentials of the electrodes are shifted to more positive (cathode) and more negative (anode) values because of a change in the a(ox-)to-a(red) ratio within the redox polymer matrix. Hence, a potential inversion occurs in the charged state (E-anode < E-cathode) and an open circuit voltage of >0.4 V is achieved and the bio-device acts as a true biosupercapacitor. The bioanode consists of a novel specifically designed high-potential Os complex modified polymer for the efficient immobilization and electrical wiring of glucose converting enzymes, such as glucose oxidase and flavin adenine dinucleotide (FAD)-dependent glucose dehydrogenase. The cathodic side is constructed from a low-potential Os complex modified polymer integrating the O-2 reducing enzyme, bilirubin oxidase. The large potential differences between the redox polymers and the prosthetic groups of the biocatalysts ensure fast and efficient charging of the biodevice.
Nyckelord
- biosupercapacitors
- energy storage
- enzyme electrodes
- Os complexes
- redox polymers
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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