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  • Gunnelin, KMittuniversitetet (author)

Assigning x-ray absorption spectra by means of soft-x-ray emission spectroscopy

  • Article/chapterEnglish1998

Publisher, publication year, extent ...

  • 1998
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:miun-2085
  • https://urn.kb.se/resolve?urn=urn:nbn:se:miun:diva-2085URI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • The possibility to symmetry assign x-ray absorption spectra using x-ray emission spectroscopy is demonstrated. The oxygen K spectra of CO2 are used to illustrate the possibility to assign core excitations through excitation-energy and angular dependence of resonantly excited x-ray emission spectra. The Rydberg-associated structures just below the ionization threshold in the O K x-ray absorption spectrum are assigned to be mainly due to excitations to orbitals of sigma(g) character. The results, which contradict some previous literature assignments, are supported by quantum-chemical calculations.

Subject headings and genre

  • HIGH-RESOLUTION
  • SYMMETRY-BREAKING
  • MOLECULAR-OXYGEN
  • STATIC EXCHANGE
  • CO2
  • POLARIZATION
  • FLUORESCENCE
  • ANISOTROPY
  • RESONANCES
  • NATURAL SCIENCES
  • NATURVETENSKAP

Added entries (persons, corporate bodies, meetings, titles ...)

  • Glans, Peter (author)
  • Skytt, P (author)
  • Guo, J.H. (author)
  • Nordgren, J (author)
  • Ågren, H (author)
  • Mittuniversitetet (creator_code:org_t)

Related titles

  • In:Physical Review A. Atomic, Molecular, and Optical Physics57:2, s. 864-8721050-2947

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