Liquid Exfoliation of Layered Materials in Water for Inkjet Printing

• MoS2 is a layered material which is abundant and non-toxic and has been increasingly studied during the last few years as a semiconducting alternative to graphene. While most studies have been performed on single MoS2 nanosheets, for example to demonstrate high-performance electronic transistors, more work is needed to explore the use of MoS2 in printed electronics. The importance of using MoS2 as a printed electronic material could be understood by considering the several orders higher electron mobility in MoS2, even in several nanometer thick layers, compared to the organic and other materials used today. In the few studies performed so far on printing MoS2, the developed dispersions used mainly organic solvents that might be detrimental for the environment. Here, we show an environmentally friendly liquid-based exfoliation method in water where the solution was stabilized by sodium dodecyl sulfate (SDS) surfactant. The dispersions consisted of very thin MoS2 nanosheets with average lateral size of about 150 nm, surface tension of 28 mN m-1 and a shelf life of a year. Although both the concentration and viscosity was less than optimal, we were able to inkjet print the MoS2 solution on paper and on PET films, using multiple printing passes. By tuning the concentration/viscosity, this approach might lead to an environmentally friendly MoS2 ink suitable for printed electronics.

Ämnesord

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

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