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Enamine/Transition ...
Enamine/Transition Metal Combined Catalysis : Catalytic Transformations Involving Organometallic Electrophilic Intermediates
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- Afewerki, Samson, 1985- (författare)
- Mittuniversitetet,Institutionen för naturvetenskap
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- Córdova, Armando, 1970- (författare)
- Mittuniversitetet,Institutionen för naturvetenskap
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(creator_code:org_t)
- 2019-11-16
- 2019
- Engelska.
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Ingår i: Topics in current chemistry. - : Springer Science and Business Media LLC. - 0340-1022 .- 1436-5049 .- 2365-0869 .- 2364-8961. ; 377:6
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Abstract
Ämnesord
Stäng
- The concept of merging enamine activation catalysis with transition metal catalysis is an important strategy, which allows for selective chemical transformations not accessible without this combination. The amine catalyst activates the carbonyl compounds through the formation of a reactive nucleophilic enamine intermediate and, in parallel, the transition metal activates a wide range of functionalities such as allylic substrates through the formation of reactive electrophilic π-allyl-metal complex. Since the first report of this strategy in 2006, considerable effort has been devoted to the successful advancement of this technology. In this chapter, these findings are highlighted and discussed.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Amino catalysis
- Combined catalysis
- Enamine catalysis
- Organocatalysis
- Transition metal catalysis
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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