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Fluid source and me...
Fluid source and methane-related diagenetic processes recorded in cold seep carbonates from the Alvheim channel, central North Sea
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Crémière, A. (author)
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Lepland, A. (author)
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Chand, S. (author)
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Sahy, D. (author)
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Kirsimäe, K. (author)
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Bau, M. (author)
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- Whitehouse, Martin J., 1962- (author)
- Naturhistoriska riksmuseet,Enheten för geovetenskap,Nordsim
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Noble, S.R. (author)
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Martma, T. (author)
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Thorsnes, T. (author)
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Brunstad, H. (author)
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(creator_code:org_t)
- Elsevier BV, 2016
- 2016
- English.
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In: Chemical Geology. - : Elsevier BV. - 0009-2541 .- 1872-6836. ; 432, s. 16-33
- Related links:
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http://www.sciencedi...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Integrated petrography, mineralogy, geochronology and geochemistry of cold seep carbonate crusts and free gas from the Alvheim channel elucidate diagenetic carbonate precipitation and related seepage histories in the central North Sea. Free gas isotope characteristics coupled with carbonate δ13C values as low as − 66‰ VPDB, indicate a predominantly microbial methane source with minor thermogenic contribution. We estimate that ~ 70% of the carbon sequestered into carbonate precipitates was derived from local oxidation of methane. The early stage of crust growth is represented by microcrystalline aragonite and Mg-calcite (10 to 40% mol MgCO3) cementing seafloor sediments consisting of clays, quartz, feldspar, and minor detrital low Mg-calcite and dolomite. Typical association of aragonite cement with coarse-grained detritus may reflect elevated fluid flow and flushing of fine particles prior to cementation close to the seafloor. Middle rare earth element enrichment in early generation microcrystalline cements containing framboidal pyrite indicates diagenetic precipitation within the zone of anaerobic methane oxidation contiguous to iron reduction. The later generation diagenetic phase corresponds to less abundant radial fibrous and botryoidal aragonite which lines cavities developed within the crusts. In contrast to early generation cements, late generation cavity infills have rare earth elements and Y patterns with small negative Ce anomalies similar to seawater, consistent with carbonate precipitation in a more open, seawater dominated system. Aragonite U–Th ages indicate carbonate precipitation between 6.09 and 3.46 kyr BP in the northern part of the channel, whereas in the southern part precipitation occurred between 1.94 and 0.81 kyr BP reflecting regional changes in fluid conduit position.
Subject headings
- NATURVETENSKAP -- Geovetenskap och miljövetenskap -- Geologi (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences -- Geology (hsv//eng)
Keyword
- The changing Earth
- Den föränderliga jorden
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Crémière, A.
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Lepland, A.
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Chand, S.
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Sahy, D.
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Kirsimäe, K.
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Bau, M.
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show more...
-
Whitehouse, Mart ...
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Noble, S.R.
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Martma, T.
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Thorsnes, T.
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Brunstad, H.
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Earth and Relate ...
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and Geology
- Articles in the publication
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Chemical Geology
- By the university
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Swedish Museum of Natural History