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Garpenbergite, Mn6□...
Garpenbergite, Mn6□As5+Sb5+O10(OH)2, a new mineral related to manganostibite, from the Garpenberg Zn–Pb–Ag deposit, Sweden
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- Holtstam, Dan, 1963- (författare)
- Naturhistoriska riksmuseet,Enheten för geovetenskap
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- Bindi, Luca, 1971- (författare)
- University of Florence
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- Förster, Hans-Jürgen (författare)
- GFZ German Research Centre for Geosciences
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- Karlsson, Andreas (författare)
- Naturhistoriska riksmuseet,Enheten för geovetenskap
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Gatedal, Kjell (författare)
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(creator_code:org_t)
- 2022-01-21
- 2022
- Engelska.
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Ingår i: Mineralogical magazine. - : Mineralogical Society. - 0026-461X .- 1471-8022. ; 86:1, s. 1-8
- Relaterad länk:
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https://nrm.diva-por... (primary) (Raw object)
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https://www.cambridg...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Garpenbergite is a new mineral (IMA2020-099) from the Garpenberg Norra mine, Hedemora, Dalarna, Sweden. It occurs with carlfrancisite and minor stibarsen, paradocrasite and filipstadite in a fractured skarn matrix of granular jacobsite, alleghanyite, kutnohorite and dolomite. Crystals are short-prismatic, up to 1.5 mm in length. They have a blackish to greyish brown colour, and are lustrous semi-opaque, with brown streak. Garpenbergite is brittle, with an uneven to subconchoidal fracture. Cleavage is distinct on {010}. Hardness ≈ 5 (Mohs) and VHN100 = 650(40). Dcalc = 4.47(1) g⋅cm−3 , overall ncalc = 1.85. Maximum specular reflectance values (%) obtained are 9.2 (470 nm), 9.1 (546 nm), 9.0 (589 nm) and 8.9 (650 nm). The empirical chemical formula of garpenbergite, based on electron microprobe data, is (Mn2+3.97Mg1.48Mn3+0.26Zn0.29)Σ6.00(As0.89Fe3+0.04Mn3+0.06Si0.01)Σ1.00(Sb0.98Fe0.02)Σ1.00O10[(OH)1.99Cl0.01]Σ2.00. The five strongest Bragg peaks in the powder X-ray diffraction pattern [d, Å(I, %) (hkl)] are 3.05 (30) (002), 2.665 (100) (161), 2.616 (40) (301), 2.586 (25) (251) and 1.545 (45) (462). The orthorhombic unit-cell dimensions (in Å) are a = 8.6790(9), b = 18.9057(19) and c = 6.1066(6), with V = 1001.99(18) Å3 for Z = 4. The crystal structure was refined from single-crystal X-ray diffraction data in the space-group Ibmm to R1 = 3.7% for 957 reflections. Garpenbergite, ideally Mn6As5+Sb5+O10(OH)2, is isostructural with manganostibite, Mn7AsSbO12, but possesses a cation vacancy (□) at an octahedrally coordinated structural site; the two minerals are thus related by the exchange Mn2+ + 2O2– → □ + 2(OH)– . The presence of hydroxyl groups is supported by vibration bands at 3647 and 3622 cm−1 in the Raman spectrum of garpenbergite, and by bond-valence considerations.
Ämnesord
- NATURVETENSKAP -- Geovetenskap och miljövetenskap -- Geologi (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences -- Geology (hsv//eng)
Nyckelord
- garpenbergit
- nytt mineral
- manganostibit
- carlfrancisit
- kristallstruktur
- kubisk tätpackning
- Ramanspektrum
- skarn
- Garpenberg
- The changing Earth
- Den föränderliga jorden
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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