Emission factors of unintentional HCB and PeCBz and their correlation with PCDD/PCDF

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Gong, WenwenSchool of Environment, Beijing Key Laboratory for Emerging Organic Contaminants Control, State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC), Tsinghua University, Beijing, China (författare)

Emission factors of unintentional HCB and PeCBz and their correlation with PCDD/PCDF

Artikel/kapitelEngelska2017

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Elsevier,2017
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LIBRIS-ID:oai:DiVA.org:oru-61469
https://urn.kb.se/resolve?urn=urn:nbn:se:oru:diva-61469URI
https://doi.org/10.1016/j.envpol.2017.05.082DOI

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Funding Agencies:NSFC-UNEP 21561142001 Program for Changjiang Scholars and Innovative Research Team in University IRT1261 Collaborative Innovation Center for Regional Environmental Quality
Hexachlorobenzene (HCB) and pentachlorobenzene (PeCBz) have been listed as unintentional POPs in the annex of the Stockholm Convention and thus, attracted attention by government and researchers. Since the intentional production and use has ceased in most countries, the unintentional releases to the environment have increased. This study gathered 206 and 78 emission factors (EFs) of unintentional HCB and PeCBz from scientific publications and governmental reports, respectively. Most of the EFs referred to the release vector "air" (EFAir) and to a less extent to "product" (EFProduct). EFs were proposed for different source categories/classes used in the Toolkit according to the technologies that released the HCB or PeCBz. Overall, lowest and highest EFAir for HCB were found in the metallurgical industry range from 1 μg/t in well controlled plants (coke, iron and steel) up to 40,000 μg/t (secondary zinc). EFs for PeCBz were in similar order of magnitude. Due to lack of data, EFs to water, land or residue cannot be proposed. Using linear regression and statistical analysis such as Pearson correlation, we found strongest correlation of EFAir between HCB and PeCBz (R(2) = 0.79, P < 0.01) and weaker, but still significant, correlations for EFAir between PCDD/PCDFTEQ and HCB (R(2) = 0.56; P < 0.01) or PeCBz (R(2) = 0.31 P < 0.01) for various thermal processes.

Ämnesord och genrebeteckningar

NATURVETENSKAP Geovetenskap och miljövetenskap Miljövetenskap hsv//swe
NATURAL SCIENCES Earth and Related Environmental Sciences Environmental Sciences hsv//eng
Hexachlorobenzene; Pentachlorobenzene; Emission factors; Unintentional formation; Correlation

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Fiedler, Heidelore,1953-Örebro universitet,Institutionen för naturvetenskap och teknik,School of Environment, Beijing Key Laboratory for Emerging Organic Contaminants Control, State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC), Tsinghua University, Beijing, China,MTM(Swepub:oru)hefr (författare)
Liu, XiaotuSchool of Environment, Beijing Key Laboratory for Emerging Organic Contaminants Control, State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC), Tsinghua University, Beijing, China (författare)
Wang, BinSchool of Environment, Beijing Key Laboratory for Emerging Organic Contaminants Control, State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC), Tsinghua University, Beijing, China (författare)
Yu, GangSchool of Environment, Beijing Key Laboratory for Emerging Organic Contaminants Control, State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC), Tsinghua University, Beijing, China (författare)
School of Environment, Beijing Key Laboratory for Emerging Organic Contaminants Control, State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC), Tsinghua University, Beijing, ChinaInstitutionen för naturvetenskap och teknik (creator_code:org_t)

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Ingår i:Environmental Pollution: Elsevier230, s. 516-5220269-74911873-6424

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Av författaren/redakt...: Gong, Wenwen; Fiedler, Heidelo ...; Liu, Xiaotu; Wang, Bin; Yu, Gang

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Av lärosätet: Örebro universitet

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