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Poly(ϵ-caprolactone...
Poly(ϵ-caprolactone) Biocomposites Based on Acetylated Cellulose Fibers and Wet Compounding for Improved Mechanical Performance
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- Lo Re, Giada, PhD, 1971- (författare)
- KTH,Biokompositer,Wallenberg Wood Science Center,Biocomposites,KTH Royal Institute of Technology, Sweden
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- Spinella, Stephen (författare)
- NYU Tandon School of Engineering, USA,NYU Tandon School of Engineering, Six Metrotech Center, Brooklyn, New York 11201, United States
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- Boujemaoui, Assya, 1983- (författare)
- KTH,Biokompositer,Wallenberg Wood Science Center,KTH Royal Institute of Technology, Sweden
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- Vilaseca, Fabiola (författare)
- University of Girona, Italy,BIMATEC Group, Department of Chemical Engineering, Agricultural and Food Technology, University of Girona, C/Maria Aurèlia Capmany 61, 17003 Girona, Spain
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- Larsson, Per Tomas (författare)
- KTH,RISE,Bioraffinaderi och energi,KTH Royal Institute of Technology, Sweden,Biokompositer,Wallenberg Wood Science Center,RISE Bioeconomy, Teknikringen 56, Stockholm, SE-100 44, Sweden
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- Adås, Fredrik (författare)
- RISE,Papperstillverkning och förpackningar,RISE Bioeconomy, Teknikringen 56, Stockholm, SE-100 44, Sweden
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- Berglund, Lars, 1979- (författare)
- KTH,Wallenberg Wood Science Center,Biokompositer,KTH Royal Institute of Technology, Sweden
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(creator_code:org_t)
- 2018-03-27
- 2018
- Engelska.
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Ingår i: ACS Sustainable Chemistry and Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 6:5, s. 6753-6760
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Poly(ϵ-caprolactone) (PCL) is a ductile thermoplastic, which is biodegradable in the marine environment. Limitations include low strength, petroleum-based origin, and comparably high cost. Cellulose fiber reinforcement is therefore of interest although uniform fiber dispersion is a challenge. In this study, a one-step wet compounding is proposed to validate a sustainable and feasible method to improve the dispersion of the cellulose fibers in hydrophobic polymer matrix as PCL, which showed to be insensitive to the presence of the water during the processing. A comparison between unmodified and acetylated cellulosic wood fibers is made to further assess the net effect of the wet feeding and chemical modification on the biocomposites properties, and the influence of acetylation on fiber structure is reported (ATR-FTIR, XRD). Effects of processing on nanofibrillation, shortening, and dispersion of the cellulose fibers are assessed as well as on PCL molar mass. Mechanical testing, dynamic mechanical thermal analysis, FE-SEM, and X-ray tomography is used to characterize composites. With the addition of 20 wt % cellulosic fibers, the Young's modulus increased from 240 MPa (neat PCL) to 1850 MPa for the biocomposites produced by using the wet feeding strategy, compared to 690 MPa showed for the biocomposites produced using dry feeling. A wet feeding of acetylated cellulosic fibers allowed even a greater increase, with an additional 46% and 248% increase of the ultimate strength and Young's modulus, when compared to wet feeding of the unmodified pulp, respectively.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Polymerteknologi (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Polymer Technologies (hsv//eng)
Nyckelord
- Acetylated cellulose
- Biocomposite
- Biodegradable
- Cellulose
- Extrusion
- Nanofibrillation
- Poly(ϵ-caprolactone)
- Wet feeding
- Acetylation
- Chemical modification
- Composite materials
- Compounding (chemical)
- Dynamic mechanical analysis
- Elastic moduli
- Feeding
- Mechanical testing
- Nanotechnology
- Natural fibers
- Textile fibers
- Thermoanalysis
- Bio-composites
- Caprolactone
- Dynamic mechanical thermal analysis
- Feeding strategies
- Hydrophobic polymers
- Mechanical performance
- Nano fibrillations
- Wood
- Chemical Engineering
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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