Continuous Processing of Nanocellulose and Polylactic Acid into Multilayer Barrier Coatings

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Koppolu, R.Åbo Akademi University, Finland,Abo Akad Univ, Ctr Funct Mat, Lab Paper Coating & Converting, SF-20500 Turku, Finland. (författare)

Continuous Processing of Nanocellulose and Polylactic Acid into Multilayer Barrier Coatings

Artikel/kapitelEngelska2019

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2019-03-04
American Chemical Society (ACS),2019
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Nummerbeteckningar

LIBRIS-ID:oai:DiVA.org:ri-38266
https://urn.kb.se/resolve?urn=urn:nbn:se:ri:diva-38266URI
https://doi.org/10.1021/acsami.9b00922DOI
https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-249810URI

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Språk:engelska
Sammanfattning på:engelska

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Ämneskategori:art swepub-publicationtype

Anmärkningar

QC 20190423
Recent years have seen an increased interest toward utilizing biobased and biodegradable materials for barrier packaging applications. Most of the abovementioned materials usually have certain shortcomings that discourage their adoption as a preferred material of choice. Nanocellulose falls into such a category. It has excellent barrier against grease, mineral oils, and oxygen but poor tolerance against water vapor, which makes it unsuitable to be used at high humidity. In addition, nanocellulose suspensions' high viscosity and yield stress already at low solid content and poor adhesion to substrates create additional challenges for high-speed processing. Polylactic acid (PLA) is another potential candidate that has reasonably high tolerance against water vapor but rather a poor barrier against oxygen. The current work explores the possibility of combining both these materials into thin multilayer coatings onto a paperboard. A custom-built slot-die was used to coat either microfibrillated cellulose or cellulose nanocrystals onto a pigment-coated baseboard in a continuous process. These were subsequently coated with PLA using a pilot-scale extrusion coater. Low-density polyethylene was used as for reference extrusion coating. Cationic starch precoating and corona treatment improved the adhesion at nanocellulose/baseboard and nanocellulose/PLA interfaces, respectively. The water vapor transmission rate for nanocellulose + PLA coatings remained lower than that of the control PLA coating, even at a high relative humidity of 90% (38 °C). The multilayer coating had 98% lower oxygen transmission rate compared to just the PLA-coated baseboard, and the heptane vapor transmission rate reduced by 99% in comparison to the baseboard. The grease barrier for nanocellulose + PLA coatings increased 5-fold compared to nanocellulose alone and 2-fold compared to PLA alone. This approach of processing nanocellulose and PLA into multiple layers utilizing slot-die and extrusion coating in tandem has the potential to produce a barrier packaging paper that is both 100% biobased and biodegradable.

Ämnesord och genrebeteckningar

TEKNIK OCH TEKNOLOGIER Materialteknik hsv//swe
ENGINEERING AND TECHNOLOGY Materials Engineering hsv//eng
barrier coatings
multilayer coatings
nanocellulose
polylactic acid
roll-to-roll process
Adhesion
Cellulose
Coatings
Extrusion
High speed cameras
Humidity control
Multilayers
Oxygen
Packaging materials
Polyesters
Suspensions (fluids)
Water vapor
Yield stress
High relative humidities
Microfibrillated cellulose
Multi-layer-coating
Oxygen transmission rates
Poly lactic acid
Water vapor transmission rate

Biuppslag (personer, institutioner, konferenser, titlar ...)

Lahti, J.Tampere University of Technology, Finland,Tampere Univ Technol, Paper Converting & Packaging, Tampere 33100, Finland. (författare)
Abitbol, TiffanyRISE,Bioraffinaderi och energi,RISE Res Inst Sweden, Bioecon Biorefinery & Energy, S-11428 Stockholm, Sweden.(Swepub:ri)tiffany.abitbol@ri.se (författare)
Swerin, AgneKTH,Yt- och korrosionsvetenskap(Swepub:kth)u1463w2g (författare)
Kuusipalo, J.Tampere University of Technology, Finland,Tampere Univ Technol, Paper Converting & Packaging, Tampere 33100, Finland. (författare)
Toivakka, M.Åbo Akademi University, Finland,Abo Akad Univ, Ctr Funct Mat, Lab Paper Coating & Converting, SF-20500 Turku, Finland. (författare)
Åbo Akademi University, FinlandAbo Akad Univ, Ctr Funct Mat, Lab Paper Coating & Converting, SF-20500 Turku, Finland. (creator_code:org_t)

Sammanhörande titlar

Ingår i:ACS Applied Materials and Interfaces: American Chemical Society (ACS)11:12, s. 11920-119271944-82441944-8252

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Av författaren/redakt...: Koppolu, R.; Lahti, J.; Abitbol, Tiffany; Swerin, Agne; Kuusipalo, J.; Toivakka, M.

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TEKNIK OCH TEKNOLOGIER: TEKNIK OCH TEKNO ...; och Materialteknik

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