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Low temperature mag...
Low temperature magneto-structural transitions in Mn3Ni20P6
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- Cedervall, Johan (author)
- Uppsala universitet,Oorganisk kemi,Uppsala University, Sweden
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- Beran, Premysl (author)
- Nuclear Physics Institute, Czech Republic,ASCR, Inst Nucl Phys, Hlavni 130, Rez 25068, Czech Republic
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- Vennström, Marie (author)
- AB Sandvik Mat Technol, SE-81181 Sandviken, Sweden
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- Danielsson, Thererse (author)
- Etteplan Sweden AB, SE-17154 Solna, Sweden
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- Ronneteg, Sabina (author)
- AB Sandvik Mat Technol, SE-81181 Sandviken, Sweden
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- Höglin, Viktor (author)
- Scienta Sauna Systems AB, Sweden,Scienta Sauna Syst AB, SE-75228 Uppsala, Sweden
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- Lindell, David (author)
- RISE,KIMAB,Swerea KIMAB AB, Box 7047, SE-16407 Kista, Sweden
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- Eriksson, Olle (author)
- Uppsala universitet,Materialteori,Uppsala University, Sweden
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- André, Gilles (author)
- CEA Saclay, LLB, F-91191 Gif Sur Yvette, France
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- Andersson, Yvonne (author)
- Uppsala universitet,Oorganisk kemi,Uppsala University, Sweden
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- Nordblad, Per (author)
- Uppsala universitet,Fasta tillståndets fysik,Uppsala University, Sweden
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- Sahlberg, Martin (author)
- Uppsala universitet,Oorganisk kemi,Uppsala University, Sweden
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(creator_code:org_t)
- Academic Press Inc. 2016
- 2016
- English.
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In: Journal of Solid State Chemistry. - : Academic Press Inc.. - 0022-4596 .- 1095-726X. ; 237, s. 343-348
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
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- X-ray and neutron powder diffraction has been used to determine the crystal and magnetic structure of Mn3Ni20P6. The crystal structure can be described as cubic with space group Fm3¯m (225) without any nuclear phase transformation within studied temperature interval from room temperature down to 4 K. The magnetic structure of Mn3Ni20P6 is complex with two independent magnetic positions for the Mn atoms and the compound passes three successive magnetic phase transitions during cooling. At 30 K the spins of the Mn atoms on the Wyckoff 4a site (Mn1) order to form a primitive cubic antiferromagnetic structure with propagation vector k=(0 0 1). Between 29 and 26 K the Mn atoms on the Wyckoff 8c site (Mn2) order independently on already ordered Mn1 magnetic structure forming a commensurate antiferromagnetic structure with propagation vector k=(0 0 12) and below 26 K, both Mn positions order to form an incommensurate helical structure with propagation vector k=(0 0 ~0.45). Magnetization vs. temperature curve of Mn3Ni20P6 shows a steep increase indicating some magnetic ordering below 230 K and a sharp field dependent anomaly in a narrow temperature range around 30 K.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Antiferromagnetism
- Magnetic structure
- Mn-compounds
- Neutron diffraction
- Antiferromagnetic materials
- Atoms
- Crystal atomic structure
- Crystallography
- Magnetism
- Manganese
- Nickel
- Temperature
- Antiferromagnetic structures
- Crystal and magnetic structure
- Helical structures
- Magnetic phase transitions
- Narrow temperature ranges
- Propagation vector
- Structural transitions
- Temperature intervals
- Crystal structure
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Cedervall, Johan
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Beran, Premysl
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Vennström, Marie
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Danielsson, Ther ...
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Ronneteg, Sabina
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Höglin, Viktor
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show more...
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Lindell, David
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Eriksson, Olle
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André, Gilles
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Andersson, Yvonn ...
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Nordblad, Per
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Sahlberg, Martin
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
- Articles in the publication
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Journal of Solid ...
- By the university
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RISE
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Uppsala University