Self-Standing, Robust Membranes Made of Cellulose Nanocrystals (CNCs) and a Protic Ionic Liquid : Toward Sustainable Electrolytes for Fuel Cells

• Energy-conversion devices based on the phenomenon of proton conduction, for example, polymer electrolyte membrane fuel cells (PEMFCs), require low cost and sustainable electrolytes with high ionic conductivity and good mechanical properties under anhydrous conditions and at temperatures up to 150 °C. Biopolymers possess an intrinsic thermomechanical stability but an insufficient proton conductivity in the dry state, which however may be imparted by a protic ionic liquid (PIL). This work presents the preparation and properties of composite membranes made of cellulose nanocrystals (CNCs) and a PIL. The membranes are thermally stable and display an ionic conductivity within the range 10-4-10-3 S/cm for temperatures between 120 and 160 °C. Moreover, the analysis of the biopolymer's apparent dimensions at nanoscale reveals a dependence of the CNCs' defects, twisting, and aggregation in the presence of the PIL. Preliminary tests using a simple fuel cell setup demonstrate a response of the membranes to the inlet of H2 gas, with a generation of electrical current. These findings provide a solid groundwork for further development and future studies of biopolymer/PIL electrolytes for energy applications. © 2021 The Authors.

Ämnesord

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

TEKNIK OCH TEKNOLOGIER  -- Materialteknik -- Keramteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Materials Engineering -- Ceramics (hsv//eng)

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik -- Annan kemiteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)

Nyckelord

cellulose nanocrystals

fuel cell

nanoscale

polymer electrolyte

protic ionic liquid

Biomolecules

Biopolymers

Cellulose

Cellulose derivatives

Composite membranes

Energy conversion

Ionic conductivity

Ionic liquids

Membranes

Polyelectrolytes

Proton exchange membrane fuel cells (PEMFC)

Anhydrous conditions

Cellulose nanocrystal (CNCs)

Energy applications

Energy conversion devices

Polymer electrolyte membrane fuel cell (PEMFCs)

Properties of composites

Protic ionic liquids

Thermomechanical stability

Solid electrolytes

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