Search: id:"swepub:oai:DiVA.org:su-110175" >
Supramolecular Tran...
-
Bueno-Alejo, Carlos J.
(author)
Supramolecular Transcription of Guanosine Monophosphate into Mesostructured Silica
- Article/chapterEnglish2014
Publisher, publication year, extent ...
-
2014-09-11
-
Wiley,2014
-
printrdacarrier
Numbers
-
LIBRIS-ID:oai:DiVA.org:su-110175
-
https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-110175URI
-
https://doi.org/10.1002/anie.201407005DOI
Supplementary language notes
-
Language:English
-
Summary in:English
Part of subdatabase
Classification
-
Subject category:ref swepub-contenttype
-
Subject category:art swepub-publicationtype
Notes
-
AuthorCount:3;
-
There is large interest in replicating biological supramolecular structures in inorganic materials that are capable of mimicking biological properties. The use of 5-guanosine monophosphate in the presence of Na+ and K+ ions as a supramolecular template for the synthesis of well-ordered mesostructured materials is reported here. Mesostructured particles with the confined template exhibit high structural order at both meso-and atomic scales, with a lower structural symmetry in the columnar mesophase. Although a chiral space group can not be deduced from X-ray diffraction, analysis by electron microscopy and circular dichroism confirms a chiral stacking arrangement along the c-axis. Guanosine monophosphate based mesophases thus illustrate the possibility for specific molecular imprinting of mesoporous materials by genetic material and the potential for higher definition in molecular recognition.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
-
Villaescusa, Luis A.
(author)
-
Garcia-Bennett, Alfonso E.Stockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)algar
(author)
-
Stockholms universitetInstitutionen för material- och miljökemi (MMK)
(creator_code:org_t)
Related titles
-
In:Angewandte Chemie International Edition: Wiley53:45, s. 12106-121101433-78511521-3773
Internet link
Find in a library
To the university's database