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Rich Coordination C...
Rich Coordination Chemistry of pi-Acceptor Dibenzoarsole Ligands
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- Gupta, Arvind Kumar (författare)
- Uppsala universitet,Oorganisk kemi
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- Akkarasamiyo, Sunisa (författare)
- Stockholms universitet,Institutionen för organisk kemi,Stockholm Univ, Dept Organ Chem, S-10691 Stockholm, Sweden.
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- Orthaber, Andreas, 1979- (författare)
- Uppsala universitet,Syntetisk molekylär kemi
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(creator_code:org_t)
- 2017-03-27
- 2017
- Engelska.
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Ingår i: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 56:8, s. 4504-4511
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A series of dibenzoarsole (also known as 9-arsafluorene) derivatives have been prepared, and their coordination chemistry has been investigated. The different ligand topology and the arsenic substituents govern the reactivity of the ligands. We report various crystal structures of palladium and platinum complexes derived from this family of ligands. The biphenyl backbone of the bridged bidentate ligands allows very flexible coordination. We have also studied the application of an allylic Pd complex in nucleophilic substitution reactions, revealing that the benzoarsole substituent is susceptible to metal insertion.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
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