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  • Luo, YiStockholms universitet,Institutionen för material- och miljökemi (MMK),Shanghai Research Institute of Petrochemical Technology, China; East China University of Science and Technology, China,Stockholms universitet, Institutionen för material- och miljökemi (MMK) (author)

Synthesis and Structure Determination of Large-Pore Zeolite SCM-14

  • Article/chapterEnglish2017

Publisher, publication year, extent ...

  • 2017-11-03
  • Wiley,2017
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:su-150894
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-150894URI
  • https://doi.org/10.1002/chem.201703361DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-470047URI

Supplementary language notes

  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • SCM-14 (Sinopec Composite Material No. 14), a new stable germanosilicate zeolite with a 12 x 8 x 8-ring channel system, was synthesized using commercially available 4-pyrrolidinopyridine as organic structure-directing agents (OSDAs) in fluoride medium. The framework structure of SCM-14 was determined using rotation electron diffraction (RED), and refined against synchrotron X-ray powder diffraction (SXPD) data for both as-made and calcined materials. The framework structure of SCM-14 is closely related to that of three known zeolites: mordenite (MOR), GUS-1 (GON), and IM-16 (UOS). SCM-14 has the same projection as that of mordenite and GUS-1 when viewed along the 12-ring channels, and possesses two more straight 8-ring channels running perpendicular to the 12-ring channels. The structure of SCM-14 can be constructed by either the same layers as that of GUS-1 or the same columns as that of IM-16. Based on their structural relationship, three topologically reasonable hypothetical zeolites were predicted.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Smeets, StefStockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholms universitet, Institutionen för material- och miljökemi (MMK)(Swepub:su)stef (author)
  • Peng, FeiStockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholms universitet, Institutionen för material- och miljökemi (MMK)(Swepub:su)fpeng (author)
  • Etman, Ahmed S.Stockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)ahet9455 (author)
  • Wang, Zhendong (author)
  • Sun, JunliangStockholms universitet,Institutionen för material- och miljökemi (MMK),Peking University, China,Stockholms universitet, Institutionen för material- och miljökemi (MMK) (author)
  • Yang, Weimin (author)
  • Stockholms universitetInstitutionen för material- och miljökemi (MMK) (creator_code:org_t)

Related titles

  • In:Chemistry - A European Journal: Wiley23:66, s. 16829-168340947-65391521-3765

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